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首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of fac-2-(4-methyl-5-phenyl#173;pyridin-2-yl)phenyl-#954;2C1,Nbis#173;2-(pyridin-2-yl)phenyl-#954;2C1,Niridium(III)
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Crystal structure of fac-2-(4-methyl-5-phenyl#173;pyridin-2-yl)phenyl-#954;2C1,Nbis#173;2-(pyridin-2-yl)phenyl-#954;2C1,Niridium(III)

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摘要

In the title compound, Ir(C11H8N)2(C18H14N), the IrIII ion adopts a distorted octa#173;hedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methyl#173;pyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a facial manner. The IrIII ion lies almost in the equatorial plane deviation = 0.0069#8197;(15)#8197;#197;. In the crystal, inter#173;molecular #960;#8211;#960; stacking inter#173;actions, as well as inter#173;molecular C#8212;H#8943;#960; inter#173;actions, are present, leading to a three-dimensional network.

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