The crystal structure of 6-(4-chloro­phen­yl)-2-(4-methyl­benz­yl)imidazo2,1-b1,3,4thia­diazole-5-carbaldehyde

Sowmya A.; Anil Kumar G.N.; Kumar S.Karki S.S.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >The crystal structure of 6-(4-chlorophenyl)-2-(4-methylbenzyl)imidazo2,1-b1,3,4thiadiazole-5-carbaldehyde

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The crystal structure of 6-(4-chlorophenyl)-2-(4-methylbenzyl)imidazo2,1-b1,3,4thiadiazole-5-carbaldehyde

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In the title imidazo2,1-b1,3,4thiadiazole derivative, C19H14ClN3OS, the 4-methylbenzyl and chlorophenyl rings are inclined to the planar imidazo2,1-b1,3,4thiadiazole moiety (r.m.s. deviation = 0.012 Å) by 64.5 (1) and 3.7 (1)°, respectively. The molecular structure is primarily stabilized by a strong intramolecular C—H⋯O hydrogen bond, leading to the formation of a pseudo-seven-membered S(7) ring motif, and a short intramolecular C—H⋯N contact forming an S(5) ring motif. In the crystal, molecules are linked by pairs of C—H⋯S hydrogen bonds, forming inversion dimers. The dimers are linked by C—H⋯O and C—H⋯π interactions, forming chains propagating along 110.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2016年第10期|1460-1462|共3页
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Sowmya A.; Anil Kumar G.N.; Kumar S.Karki S.S.;
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The crystal structure of 6-(4-chloro­phen­yl)-2-(4-methyl­benz­yl)imidazo2,1-b1,3,4thia­diazole-5-carbaldehyde

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The crystal structure of 6-(4-chlorophenyl)-2-(4-methylbenzyl)imidazo2,1-b1,3,4thiadiazole-5-carbaldehyde