2-Amino-5-chloro­pyridinium cis-diaqua­dioxalatochromate(III) sesquihydrate

Chérif I.; Abdelhak J.; Zid M.F.Driss A.

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2-Amino-5-chloropyridinium cis-diaquadioxalatochromate(III) sesquihydrate

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In the crystal structure of the title compound, (C5H6ClN2)Cr(C2O4)2(H2O)2·1.5H2O, the CrIII atom adopts a distorted octahedral geometry being coordinated by two O atoms of two cis water molecules and four O atoms from two chelating oxalate dianions. The cis-diaquadioxalatochromate(III) anions, 2-amino-5-chloropyridinium cations and uncoordinated water molecules are linked into a three-dimensional supramolecular array by O—H⋯O and N—H⋯O hydrogen-bonding interactions. One of the two independent lattice water molecules is situated on a twofold rotation axis.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2012年第6期|m824-m825|共页
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Chérif I.; Abdelhak J.; Zid M.F.Driss A.;
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2-Amino-5-chloro­pyridinium cis-diaqua­dioxalatochromate(III) sesquihydrate

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2-Amino-5-chloropyridinium cis-diaquadioxalatochromate(III) sesquihydrate