Additivity Rule Holds in Supercooling of Aqueous Solutions

H.Kanno; K.Miyata; K.TomizawaH.Tanaka

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Additivity Rule Holds in Supercooling of Aqueous Solutions

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Homogeneous ice nucleation temperatures (T_H) of aqueous solutions of methanol,ethylene glycol,glycerol,xylitol,poly(ethylene glycol)s,glucose,and fructose were measured as a function of solute concentration.It is shown that the additivity rule holds fairly well for the T_H values of the solutions of the same chemical family.Contrary to the conclusion by Koop et al.(ref 11),T_H depends strongly on the nature of a solute.It is confirmed that there is a linear relation between T_H and melting temperature (T_m) of the solution (solute:methanol,ethylene glycol or glycerol) up to high solute concentrations.

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2004年第28期|6079-6082|共4页
作者
H.Kanno; K.Miyata; K.TomizawaH.Tanaka;
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Department of Applied Chemistry and Department of Applied Physics,National Defense Academy,Yokosuka 239-8686,Japan;

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正文语种英语
中图分类物理化学（理论化学）、化学物理学;
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Additivity Rule Holds in Supercooling of Aqueous Solutions

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