Orientational disorder in the one-dimensional coordination polymer catena-polybis­(acetyl­acetonato-κ2O,O′)cobalt(II)-μ-1,4-di­aza­bicyclo­2.2.2octane-κ2N1:N4

Dumitru F.; Englert U.; Braun B.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Orientational disorder in the one-dimensional coordination polymer catena-polybis(acetylacetonato-κ2O,O′)cobalt(II)-μ-1,4-diazabicyclo2.2.2octane-κ2N1:N4

【24h】

Orientational disorder in the one-dimensional coordination polymer catena-polybis(acetylacetonato-κ2O,O′)cobalt(II)-μ-1,4-diazabicyclo2.2.2octane-κ2N1:N4

机译：

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The title compound, Co(C5H7O2)2(C6H12N2)n, was obtained as a one-dimensional coordination polymer from bis(acetylacetonato)diaquacobalt(II), Co(acac)2(OH2)2, and 1,4-diazabicyclo2.2.2octane (DABCO), a diamine with good bridging ability and rod-like spacer function. In the chain complex that extends along the c axis, the CoII atom is six-coordinated, the O-donor atoms of the chelating acac ligands occupying the equatorial positions and the bridging DABCO ligands being in trans-axial positions. In the crystal structure, the DABCO ligand is conformationally disordered in a 50:50 manner as a result of its location across a crystallographic mirror plane. The metal–metal distance is very close to that in a related compound exhibiting weak antiferromagnetic exchange between the CoII ions, and the title compound can thus be useful for obtaining more information about the contribution of different bridges to the magnetic coupling between paramagnetic ions.

著录项

来源
《Acta Crystallographica Section E: Crystallographic Communications》 |2016年第4期|548-551|共4页
作者
Dumitru F.; Englert U.; Braun B.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类
关键词

相似文献

外文文献

1. Orientational disorder in the one-dimensional coordination polymer catena-poly[[bis-(acetyl-acetonato-κ2O,O′)cobalt(II)]-μ-1,4-di-aza-bicyclo-[2.2.2]octane-κ2N1:N4] [J] . Dumitru F., Englert U., Braun B. Acta Crystallographica Section E: Crystallographic Communications . 2016,第4期

机译：一维配位聚合物链-聚[[双-（乙酰-乙酰丙酮-κ2O，O'）钴（II）]-μ-1,4-二氮杂-双环-[2.2.2]辛烷的取向紊乱-κ2N1：N4]
2. Di‐μ‐chloro‐bis(aza‐4 azonia‐1 bicyclo2.2.2octane)dichloromanganèse(II) [J] . B. Viossat, P. Khodadad, N. Rodier Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications . 1988,第5期

机译：Di‐μ‐chloro‐bis(aza‐4 azonia‐1 bicyclo2.2.2octane)dichloromanganèse(II)
3. Structure d'une nouvelle variété de di‐μ‐chloro‐bis(aza‐4 azonia‐1 bicyclo2.2.2octane)dichloromanganèse(II) [J] . B. Viossat, P. Khodadad, N. Rodier Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications . 1988,第7期

机译：Structure d'une nouvelle variété de di‐μ‐chloro‐bis(aza‐4 azonia‐1 bicyclo2.2.2octane)dichloromanganèse(II)
4. Orientational disorder in the one-dimensional coordination polymer catena-poly[[bis(acetylacetonato-κ2O,O′)cobalt(II)]-μ-1,4-diazabicyclo[2.2.2]octane-κ2N1:N4] [O] . Florina Dumitru, Ulli Englert, Beatrice Braun 2016

机译：一维配位聚合物catena-poly [[bis（acetylacetonato-κ2O，O'）cobalt（II）] - μ-1,4-diazabicyclo [2.2.2]辛烷-κ2N1：N4]中的取向紊乱

Orientational disorder in the one-dimensional coordination polymer catena-polybis­(acetyl­acetonato-κ2O,O′)cobalt(II)-μ-1,4-di­aza­bicyclo­2.2.2octane-κ2N1:N4

摘要

著录项

相似文献

相关主题

期刊订阅

Orientational disorder in the one-dimensional coordination polymer catena-polybis(acetylacetonato-κ2O,O′)cobalt(II)-μ-1,4-diazabicyclo2.2.2octane-κ2N1:N4