Crystal structure of catena-polybis#173;#956;3-2-(2-nitro#173;phen#173;yl)acetato-#954;3O:O:O#8242;disilver(I)

Danish M.; Tahir M.N.; Iftikhar S.Ahmad N.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of catena-polybis#173;#956;3-2-(2-nitro#173;phen#173;yl)acetato-#954;3O:O:O#8242;disilver(I)

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Crystal structure of catena-polybis#173;#956;3-2-(2-nitro#173;phen#173;yl)acetato-#954;3O:O:O#8242;disilver(I)

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The title compound, Ag2(C8H6NO4)2n, is a silver complex of 2-(2-nitro#173;phen#173;yl)acetic acid. The mol#173;ecules are not conventional crystallographic inversion dimers but consist of two independent ligands and two AgI ions, each with a distorted T-shaped coordination environment. The dihedral angles between acetate groups and the benzene rings are 51.1#8197;(2) and 57.9#8197;(2)#176;. The nitro groups are oriented at dihedral angles of 23.6#8197;(5) and 32.3#8197;(3)#176; with respect to the parent benzene rings. The dimers form polymeric chains along the a-axis direction. The Ag#8943;Ag separation within a dimer is 2.8200#8197;(5) and between symmetry-related dimers is 3.6182#8197;(5)#8197;#197;. The polymeric chains are inter#173;linked by C#8212;H#8943;O hydrogen-bond inter#173;actions.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第5期|共页
作者
Danish M.; Tahir M.N.; Iftikhar S.Ahmad N.;
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作者单位

Department of Chemistry, Institute of Natural Sciences, University of Gujrat, Gujrat 50700, Pakistan;

Department of Physics, University of Sargodha, Sargodha, Punjab, Pakistan;

State Key Laboratory of Materials, Synthesis and New Technology, Wuhan University of Technology, Wuhan 430070, China;

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CRYSTAL STRUCTURE; SILVER(I) COMPLEX; 2-(2-NITROPHENYL)ACETIC ACID; HYDROGEN BONDING;

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机译：catena-Poly [disilver（I）（Ag-Ag）-bis（μ3-quinoline-3-carboxylato）-1：2：1′κ3O：O′：N; 2：1′′：2′′κ3N：O ：O']
2. catena-Poly[disilver(I)(Ag–Ag)-bis(μ3-quinoline-3-carboxylato)-1:2:1′κ3O:O′:N;2:1′′:2′′κ3N:O:O′] [J] . Cong Y., Liu C.-B., Sun H.-Y. Acta Crystallographica Section E: Crystallographic Communications . 2012,第9期

机译：catena-Poly [disilver（I）（Ag-Ag）-bis（μ3-quinoline-3-carboxylato）-1：2：1′κ3O：O′：N; 2：1′′：2′′κ3N：O ：O']
3. catena-Poly[[diaquacalcium]bis[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ3O,O′:O;κ3O:O,O′] [J] . Bhatti M.H., Saeed S., Shah S.R., Acta Crystallographica Section E: Crystallographic Communications . 2011,第8期

机译：catena-Poly [[diadiacalcium] bis [μ-2-（1,3-dioxoisoindolin-2-yl）acetateacetate]-κ3O，O'：O;κ3O：O，O']
4. catena-Polydisilver(I)(Ag–Ag)-bis(μ3-quinoline-3-carboxylato)-1:2:1′κ3O:O′:N;2:1′′:2′′κ3N:O:O′ [O] . Chun-Bo Liu, Yao Cong, He-Yi Sun 2012

机译：catena-Poly disilver（I）（Ag–Ag）-bis（μ3-喹啉-3-羧基carboxy）-1：2：1′κ3O：O′：N; 2：1′′：2′′κ3N：O：O
5. catena-Poly[[[(acetato-κ2O,O′)cadmium]-μ-acetato-κ3O,O′:O′-μ-{1,2-bis[4-(pyridin-3-yl)pyrimidin-2-ylsulfanyl]ethane}-κ2N4,N4′] trihydrate] [O] . Hua-Ze Dong, Zhao-Lian Chu 2011

机译：catena-Poly [[[（（acetato-＆＃954; 2O，O＆＃8242;）镉]-＆＃956; -acetato-＆＃954; 3O，O＆＃8242 ;: O＆＃8242;-＆＃956; -{1,2-双[4-（吡啶-3-基）嘧啶-2-基硫烷基]乙烷}-＆＃954; 2N4，N4＆＃8242;]三水合物]

Crystal structure of catena-polybis#173;#956;3-2-(2-nitro#173;phen#173;yl)acetato-#954;3O:O:O#8242;disilver(I)

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