Crystal structure of N1-phenyl-N4-(E)-(pyren-1-yl)methyl#173;idenebenzene-1,4-di#173;amine

Faizi M.S.H.; Prisyazhnaya E.V.

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Crystal structure of N1-phenyl-N4-(E)-(pyren-1-yl)methyl#173;idenebenzene-1,4-di#173;amine

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In the title compound, C29H20N2, the dihedral angles subtended by the central p-phenyl#173;enedi#173;amine ring with respect to the mean plane of the terminal pyrenyl ring system (r.m.s. deviation = 0.027#8197;#197;) and the terminal N-phenyl ring are 29.34#8197;(4) and 43.43#8197;(7)#176;, respectively. The conformation about the C#61;N bond is E. In the crystal, mol#173;ecules are linked by N#8212;H#8943;#960; and C#8212;H#8943;#960; inter#173;actions forming chains propagating along the 10-2 direction. These chains are linked via #960;#8211;#960; inter#173;actions inter-centroid distances are in the range 3.5569#8197;(11)#8211;3.708#8197;(1)#8197;#197;, forming slabs lying parallel to (30-4).

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第3期|261-263|共3页
作者
Faizi M.S.H.; Prisyazhnaya E.V.;
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作者单位

Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, India;

Department of Chemistry, Kyiv National University of Construction and Architecture, Povitroflotsky Avenue 31, 03680 Kiev, Ukraine;

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CRYSTAL STRUCTURE; N-PHENYL-P-PHENYLENEDIAMINE; 1-PYRENECARBOXALDEHYDE; PMBD; SCHIFF BASE; N-H...PI AND C-H...PI INTERACTIONS; PI-PI INTERACTIONS;

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Crystal structure of N1-phenyl-N4-(E)-(pyren-1-yl)methyl#173;idenebenzene-1,4-di#173;amine

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