SrMnII2MnIII(PO4)3

Alhakmi G.; Assani A.; El Ammari L.Follet C.Saadi M.

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SrMnII2MnIII(PO4)3

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The title compound, strontium trimanganese tris(orthophosphate), was synthesized under hydrothermal conditions. Its structure is isotypic to that of the lead analogue PbMnII2MnIII(PO4)3. Two O atoms are in general positions, whereas all others atoms are in special positions. The Sr and one P atom exhibit mm2 symmetry, the MnII atom 2/m symmetry, the MnIII atom and the other P atom .2. symmetry and two O atoms are located on mirror planes. The three-dimensional network of the crystal structure is made up of two types of chains running parallel to 010. One chain is linear and is composed of alternating MnIIIO6 octahedra and PO4 tetrahedra sharing vertices; the other chain has a zigzag arrangement and is built up from two edge-sharing MnIIO6 octahedra connected to PO4 tetrahedra by edges and vertices. The two types of chains are linked through PO4 tetrahedra, leading to the formation of channels parallel to 100 and 010 in which the SrII ions are located. They are surrounded by eight O atoms in the form of a slightly distorted bicapped trigonal prism.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2013年第9期|i56-i56|共页
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Alhakmi G.; Assani A.; El Ammari L.Follet C.Saadi M.;
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机译：金属水平3D MT框架结构化学。模板Ga2（PO4）2F2和GA2（PO4）2（HF）F2和GA2（PO4）2（HF）F2和GA2（PO4）2（HF）F2（NH 4）2 [GA2（PO4）2F2]（CTR帧类型）和（NH4）2 [GA2（PO4）2（HF）F2]（帧R-CTR的类型）
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机译：Fluorapatite Ca5（pO4）3F和sr5（pO4）3F中对称保留电荷补偿和空位的点电荷分析

SrMnII2MnIII(PO4)3

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