Ethylene polymerization by the thermally unique 1-2-(bis(4-fluoro phenyl)methyl)-4,6-dimethylphenylimino-2-aryliminoacenaphthylnickel precursors

Du Shizhen; Xing Qifeng; Flisak ZygmuntYue ErlinSun YangSun Wen-Hua

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Ethylene polymerization by the thermally unique 1-2-(bis(4-fluoro phenyl)methyl)-4,6-dimethylphenylimino-2-aryliminoacenaphthylnickel precursors

【24h】

Ethylene polymerization by the thermally unique 1-2-(bis(4-fluoro phenyl)methyl)-4,6-dimethylphenylimino-2-aryliminoacenaphthylnickel precursors

机译：

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A series of 1-2-(bis(4-fluorophenyl)methyl)-4,6-dimethylphenylimino-2-aryliminoacenaphthylene derivatives together with the corresponding nickel bromide complexes was synthesized and characterized. Representative complexes C2 and C5 were characterized by the single-crystal X-ray diffraction, revealing a distorted tetrahedral geometry. Upon activation with either methylaluminoxane (MAO) or ethylaluminum sesquichloride (EASC), all nickel complexes exhibited high activities towards ethylene polymerization, producing polyethylene with a relatively low degree of branching and narrow polydispersity. Complex C1 maintained good activity at elevated reaction temperatures, which indicates significant thermal stability of the active species.

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2015年第27期|12282-12291|共10页
作者
Du Shizhen; Xing Qifeng; Flisak ZygmuntYue ErlinSun YangSun Wen-Hua;
展开▼
作者单位

Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. 2-(1-(2,4-Bis((di(4-fluorophenyl)methyl)-6- methylphenylimino)ethyl)-6-(1-(arylimino) ethyl)pyridylmetal (iron or cobalt) Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior [J] . Wenjuan Zhang, Shaoli Wang, Shizhen DuCun-Yue GuoXiang HaoWen-Hua Sun Macromolecular chemistry and physics . 2014,第18期

机译：2-(1-(2,4-Bis((di(4-fluorophenyl)methyl)-6- methylphenylimino)ethyl)-6-(1-(arylimino) ethyl)pyridylmetal (iron or cobalt) Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior
2. Polarized twisted ethylenes: structures of 3‐bis(dimethylamino)methylene‐3‐phenyl‐2‐propanone (I), C14H20N2O, and methyl 2‐bis(dimethylamino)methylene‐3‐oxobutyrate trihydrate (II), C14H18N2O3.3H2O [J] . N. U. Kamath, K. Venkatesan Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications . 1984,第3期

机译：Polarized twisted ethylenes: structures of 3‐bis(dimethylamino)methylene‐3‐phenyl‐2‐propanone (I), C14H20N2O, and methyl 2‐bis(dimethylamino)methylene‐3‐oxobutyrate trihydrate (II), C14H18N2O3.3H2O
3. 1R)-2-((3R,4S)-3-Methyl-4-(N-phenyl-N-propionylamino)piperidin-1-yl)-1-ph enylethyl p-bromobenzoate and N-((3R,4S)-1-((2S)-2-(4-bromophenyl)-2-hydroxyethyl)-3-methyl-piperidin-4- yl)-N-phenylacrylamide. [J] . Deschamps JR, George C, Flippen Anderson JL Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications . 2002,第6期

机译：1R)-2-((3R,4S)-3-Methyl-4-(N-phenyl-N-propionylamino)piperidin-1-yl)-1-ph enylethyl p-bromobenzoate and N-((3R,4S)-1-((2S)-2-(4-bromophenyl)-2-hydroxyethyl)-3-methyl-piperidin-4- yl)-N-phenylacrylamide.
4. 1-(E)-2-(2-Hydroxy-5-methylphenyl)diazen-2-ium-1-ylnaphthalen-2-olate [O] . Souheyla Chetioui, Issam Boudraa, Sofiane Bouacida, 2013

机译：1-（（E）-2-（2-Hydrdroxy-5-methylphenyl））diazen-2-ium-1-yl萘-2-油酸酯
5. 1-[Morpholino(phenyl)methyl]-2-naphthol [O] . Min Min Zhao, Ping Ping Shi 2010

机译：1- [Morpholino（phenyl）methyl] -2-萘酚

Ethylene polymerization by the thermally unique 1-2-(bis(4-fluoro phenyl)methyl)-4,6-dimethylphenylimino-2-aryliminoacenaphthylnickel precursors

摘要

著录项

相似文献

相关主题

期刊订阅