Tuning the overpotential of electrocatalytically active cyclopentadienylnickel complexes containing 1,4-diaza-1,3-butadienes (DAB) for proton reduction

Sondermann Christina; Ringenberg Mark R.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Tuning the overpotential of electrocatalytically active cyclopentadienylnickel complexes containing 1,4-diaza-1,3-butadienes (DAB) for proton reduction

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Tuning the overpotential of electrocatalytically active cyclopentadienylnickel complexes containing 1,4-diaza-1,3-butadienes (DAB) for proton reduction

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摘要

The complexes CpNi(DAB)BF4, Cp = cyclopentadienyl, DAB = substituted 1,4-diaza- 1,3-butadienes, undergo two reduction processes. EPR spectroscopically active Ni(I) intermediates were observed despite the potential redox activity of the DAB ligands and these reduced species catalyse the conversion of electrons and protons (from acetic acid) into dihydrogen.

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第16期|5143-5146|共4页
作者
Sondermann Christina; Ringenberg Mark R.;
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Univ Stuttgart, Inst Anorgan Chem, Pfaffenwaldring 55, D-70550 Stuttgart, Germany;

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正文语种英语
中图分类化学;无机化学;
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Tuning the overpotential of electrocatalytically active cyclopentadienylnickel complexes containing 1,4-diaza-1,3-butadienes (DAB) for proton reduction

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