A copper-phosphonate network as a high-performance heterogeneous catalyst for the CO2 cycloaddition reactions and alcoholysis of epoxides

Ai Jing; Min Xue; Gao Chao-YingTian Hong-RuiDang SongSun Zhong-Ming

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A copper-phosphonate network as a high-performance heterogeneous catalyst for the CO2 cycloaddition reactions and alcoholysis of epoxides

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摘要

A novel 3D copper-phosphonate network, with the general formula Cu-7(H1L)(2)(TPT)(3)(H2O)(6), namely compound 1, has been synthesized using a rigid tetrahedral linker tetraphenylsilane tetrakis-4-phosphonic acid (H8L) and a nitrogen-containing ancillary ligand (TPT: 5-(4-(1H-1,2,4-triazol-1-yl) phenyl)-1H-tetrazole) under hydrothermal conditions. The compound was fully characterized using PXRD, ICP, IR, TGA and elemental analysis. Compound 1 can be used as an efficient catalyst for the CO2 coupling reaction that is greatly superior to many conventional MOF-based catalysts, where porosity is always mentioned and used. In addition, it shows excellent catalytic performance for ring-opening reactions with epoxides under ambient conditions. Additionally, compound 1 can be recycled at least three times without a significant compromise in the activity in the two catalytic reactions.

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第20期|6756-6761|共6页
作者
Ai Jing; Min Xue; Gao Chao-YingTian Hong-RuiDang SongSun Zhong-Ming;
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作者单位

Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China;

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正文语种英语
中图分类化学;无机化学;
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A copper-phosphonate network as a high-performance heterogeneous catalyst for the CO2 cycloaddition reactions and alcoholysis of epoxides

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