Liquid/vapor-induced reversible dynamic structural transformation of a three-dimensional Cu-based MOF to a one-dimensional MOF showing gate adsorption

Kondo Atsushi; Suzuki Takayuki; Kotani RyosukeMaeda Kazuyuki

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Liquid/vapor-induced reversible dynamic structural transformation of a three-dimensional Cu-based MOF to a one-dimensional MOF showing gate adsorption

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A new 3D metal-organic framework (MOF), in which 2D layers are interlaced to form a 3D architecture, was synthesized by a reaction of Cu(BF4)(2) and 1,3-bis(4-pyridyl) propane (bpp) in a water/1-hexanol solvent system, and the crystal structure of the MOF was successfully solved. The MOF is reversibly transformed to a 1D chain MOF, which shows gate adsorption properties. The dynamic transformation gives crystal size reduction resulting in a slight change in CO2 adsorption isotherms. The 1D MOF shows selective adsorption/separation properties on benzene and its analogues with similar sizes and shapes (benzene, toluene, and cyclohexane).

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第20期|6762-6768|共7页
作者
Kondo Atsushi; Suzuki Takayuki; Kotani RyosukeMaeda Kazuyuki;
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Tokyo Univ Agr & Technol, Inst Engn, Dept Appl Chem, 2-24-16 Naka Cho, Koganei, Tokyo 1848588, Japan;

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正文语种英语
中图分类化学;无机化学;
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Liquid/vapor-induced reversible dynamic structural transformation of a three-dimensional Cu-based MOF to a one-dimensional MOF showing gate adsorption

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