Hydrogen atom transfer reactions of ferrate(VI) with phenols and hydroquinone. Correlation of rate constants with bond strengths and application of the Marcus cross relation

Xie Jianhui; Ma Li; Lam William W. Y.Lau Kai-ChungLau Tai-Chu

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Hydrogen atom transfer reactions of ferrate(VI) with phenols and hydroquinone. Correlation of rate constants with bond strengths and application of the Marcus cross relation

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The oxidation of phenols by HFeO4- proceeds via a hydrogen atom transfer (HAT) mechanism, as evidenced by a large deuterium isotope effect and a linear correlation between the log(rate constant) and bond dissociation free energy (BDFE) of phenols. The Marcus cross relation has been applied to predict the rate constant of HAT from hydroquinone to HFeO4-.

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第1期|70-73|共4页
作者
Xie Jianhui; Ma Li; Lam William W. Y.Lau Kai-ChungLau Tai-Chu;
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City Univ Hong Kong, Dept Biol & Chem, Kowloon, Hong Kong, Peoples R China;

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正文语种英语
中图分类化学;无机化学;
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Hydrogen atom transfer reactions of ferrate(VI) with phenols and hydroquinone. Correlation of rate constants with bond strengths and application of the Marcus cross relation

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