Synthesis of water-soluble palladium(II) complexes with N-heterocyclic carbene chelate ligands and their use in the aerobic oxidation of 1-phenylethanol

Asensio Juan M.; Gomez-Sal Pilar; Andres Romande Jesus Ernesto

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Synthesis of water-soluble palladium(II) complexes with N-heterocyclic carbene chelate ligands and their use in the aerobic oxidation of 1-phenylethanol

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The synthesis of palladium(II) complexes containing N-heterocyclic carbene chelate ligands is reported. These chelate ligands have methylene or ethylene ring bridges and sulfonate, carbonate or ammonium functionalities to render the complexes soluble in water. Bis- (bis-NHC)PdX2 (X = Cl, Br or I) and tetra-carbene (bis-NHC)(2)Pd complexes have been prepared and the crystal structures of two of them have been determined. The NHC ligand is coordinated to the metal center in normal (C2-bound) or abnormal (C4-bound) mode. Processes involving the formation of NHC-Pd bonds or the transfer of NHC ligands have been explored in water. The behavior of the bis-carbene complexes as catalysts for the aerobic oxidation of 1-phenylethanol is also discussed.

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《Dalton transactions: An international journal of inorganic chemistry》 |2017年第20期|6785-6797|共13页
作者
Asensio Juan M.; Gomez-Sal Pilar; Andres Romande Jesus Ernesto;
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Univ Alcala De Henares, Dept Quim Organ & Quim Inorgan, Madrid 28871, Spain;

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正文语种英语
中图分类化学;无机化学;
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Synthesis of water-soluble palladium(II) complexes with N-heterocyclic carbene chelate ligands and their use in the aerobic oxidation of 1-phenylethanol

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