Effects of barium on the performance of secondary alkaline zinc electrode

Zheng Y.; Wang JM.; Chen H.Zhang JQ.Cao CN.

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Effects of barium on the performance of secondary alkaline zinc electrode

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The active material of secondary alkaline zinc electrode with barium additives was prepared by a chemical reaction method and characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The electrochemical performance of various pasted Zn electrodes was investigated by cyclic voltammetry, charge/discharge method and electrochemical impedance spectroscopy (EIS). The addition of barium can synthesize a compound barium zincate with the molecular structure of BaZn(OH)(4)(.)xH(2)O, which turns into another molecular structure of BaZnO2 after heat treatment, and improve the discharge performance. The EIS of the various Zn electrodes show two time constants besides diffusion impedance including a state variable representing the covering degree of ZnO on the electrode surface. (C) 2003 Elsevier B.V. All rights reserved. References: 40

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《Materials Chemistry and Physics》 |2004年第1期|99-106|共8页
作者
Zheng Y.; Wang JM.; Chen H.Zhang JQ.Cao CN.;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种英语
中图分类工程材料学;
关键词
Barium zincate; Pasted zinc electrode; Zinc oxide; Eis; Ni-zn cells; Impedance plane displays; Zn/niooh cells; Cycle life; Stability conditions; Calcium hydroxide; Steady-state; Silver-zinc; Batteries; Additives;

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Effects of barium on the performance of secondary alkaline zinc electrode

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