Body-wing swapping in butterfly {Fe~(III) _2Ln ~(III) _2} coordination clusters with triethylene glycol as ligand

Peng G.; Kostakis G.E.; Lan Y.Powell A.K.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Body-wing swapping in butterfly {Fe~(III) _2Ln ~(III) _2} coordination clusters with triethylene glycol as ligand

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Body-wing swapping in butterfly {Fe~(III) _2Ln ~(III) _2} coordination clusters with triethylene glycol as ligand

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The first use of triethylene glycol (H_2teg) in Fe/Ln chemistry affords two series of tetranuclear {Fe~(III))2Ln ~(III) _2} coordination clusters possessing defect-dicubane cores. A change in the synthetic procedure results in a different arrangement of the relative positions of the 3d and 4f elements offering a means to steer the structural and electronic features within a 3d-4f system.

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第1期|46-49|共4页
作者
Peng G.; Kostakis G.E.; Lan Y.Powell A.K.;
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Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermannvon-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany;

Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany;

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中图分类化学;
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Body-wing swapping in butterfly {Fe~(III) _2Ln ~(III) _2} coordination clusters with triethylene glycol as ligand

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