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Evaluation of the growth condition of chemical vapour deposition diamond under fluorine addition

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Effects of fluorine addition on the growth conditions of chemical vapour deposition (CVD) diamond are discussed in the Light of thermodynamics. Phase diagrams in the C-H-F system for low-pressure diamond growth are calculated in the usual conditions: 0.1-6.67 kPa, 900-1100 K. The effects of substrate temperature and fluorine addition on the diamond growth region are explored. From these phase diagrams, we find that the diamond growth region is small and near the CH4-HF line at low temperature; it gradually moves to the H-HF line with increasing temperature. (C) 1998 Elsevier Science S.A. All rights reserved. References: 18

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