Electroplated synthesis of Ni-P-UFD, Ni-P-CNTs, and Ni-P-UFD-CNTs composite coatings as hydrogen evolution electrodes

Shi  YL; Yang  Z; Li  MKXu  HLi  HL

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Electroplated synthesis of Ni-P-UFD, Ni-P-CNTs, and Ni-P-UFD-CNTs composite coatings as hydrogen evolution electrodes

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Ni-P-ultrafine diamond (UFD), Ni-P-carbon nanotubes (CNTs), and Ni-P-UFD-CNTs composite coatings have been electroplated and their hydrogen evolution reaction was studied. Ni-P-CNTs performed the highest catalytic activity though all of the composite electrodes were more active than the Ni-P electrode, which is tightly related to their structures dissolved by hydrogen when prepared. With increasing temperature, the ability of hydrogen evolution of the electrodes was promoted. UFD and CNTs played a cooperating role. The effect of beat treatment was also determined, it is disadvantageous in alkaline environment while not in acid solution. (C) 2004 Elsevier B.V. All rights reserved.

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来源
《Materials Chemistry and Physics》 |2004年第1期|154-161|共8页
作者
Shi YL; Yang Z; Li MKXu HLi HL;
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作者单位

Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种英语
中图分类工程材料学;
关键词
Ni-P-UFD composite; Ni-P-CNTs composite; thin films; hydrogen evolution; CARBON NANOTUBES; DIAMOND FILMS; EMISSION; SORPTION; STORAGE; ALLOYS;

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Electroplated synthesis of Ni-P-UFD, Ni-P-CNTs, and Ni-P-UFD-CNTs composite coatings as hydrogen evolution electrodes

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