Smallest optical gap for quasi-one-dimensional iodo-bridged platinum compounds

Shin M.; Takaishi S.; Kumagai S.Ueda Y.Breedlove B.K.Matsuzaki H.Okamoto H.Wakabayashi Y.Yamashita M.

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Smallest optical gap for quasi-one-dimensional iodo-bridged platinum compounds

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摘要

We synthesized a series of one-dimensional (1D) iodo-bridged platinum compounds with long alkyl chains on the counterions. In the compounds, the shortest Pt?Pt distance and the smallest band gap thus far reported were achieved. These compounds were found to be in a CDW state by using synchrotron X-ray diffraction measurements.

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第18期|6277-6280|共4页
作者
Shin M.; Takaishi S.; Kumagai S.Ueda Y.Breedlove B.K.Matsuzaki H.Okamoto H.Wakabayashi Y.Yamashita M.;
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作者单位

Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba Aramaki, Aoba-ku, Sendai 980-8578, Japan;

Department of Advanced Materials Science, Graduate School of Frontier Sciences, University of Tokyo, Kashiwa 277-8561, Japan;

Division of Materials Physics, Graduate School of Engineering Science, Osaka University Toyonaka, Osaka 560-8531, Japan;

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原文格式 PDF
正文语种英语
中图分类化学;
关键词
quasi-one-dimensional; CDW; X-ray;

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Smallest optical gap for quasi-one-dimensional iodo-bridged platinum compounds

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