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A novel EVA composite with simultaneous flame retardation and ceramifiable capacity

机译:同时阻燃和可陶瓷化的新型EVA复合材料

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Ethylene-vinyl acetate (EVA) filled with glass dust (GD), glass fiber (GF), OMMT, and melamine cyanurate (MCA) was developed as a ceramifiable flame-retardant polymer composite for cables and insulated wires. The ceramics formed at different high temperatures based on the ceramifiable flame-retardant polymer composites were investigated by mechanical testing, scanning electron microscopy (SEM), and energy dispersive X-ray (EDX) spectroscopy; the flame retardation of the ceramifiable flame-retardant EVA composites was studied with the aid of vertical burning testing (UL-94), limiting oxygen index (LOI), and cone calorimeter (CC) tests. The results showed that the ceramics were prepared successfully at different high temperatures based on the ceramifiable flame-retardant polymer composites. For the EVA/GD/GF/OMMT/MCA system with a weight ratio of 35/26/9/5/25, the ceramic formed at 800 degrees C had a flexural strength of 13.82 MPa, and both a UL-94 V-0 rating and a LOI of 28.2% were achieved. Moreover, CC results confirmed that the heat release rate (HRR), total release rate (THR), smoke production rate (SPR), and mass loss rate (MLR) of the composite were reduced significantly compared with the corresponding value of neat EVA or the ceramifiable EVA composite without MCA. The dilatometric experiment analysis, SEM, and viscosity analysis demonstrated that a eutectic mixture resulting from GD and GF led to the formation of ceramics at high temperature. Thermal gravimetric analysis (TG), etc. illustrated that both the release of a large amount of non-flammable gas and the presence of OMMT led to the much better flame retardancy of EVA/GD/GF/OMMT/MCA than that of neat EVA or the ceramifiable EVA composites without MCA.
机译:填充有玻璃粉尘(GD),玻璃纤维(GF),OMMT和三聚氰胺氰尿酸酯(MCA)的乙烯-乙酸乙烯酯(EVA)是一种可陶瓷化的阻燃聚合物复合材料,用于电缆和绝缘电线。通过机械测试,扫描电子显微镜(SEM)和能量色散X射线(EDX)光谱研究了基于可陶瓷阻燃聚合物复合材料在不同高温下形成的陶瓷。通过垂直燃烧测试(UL-94),极限氧指数(LOI)和锥形量热仪(CC)测试研究了可陶瓷阻燃EVA复合材料的阻燃性。结果表明,基于可陶瓷阻燃聚合物复合材料,成功地在不同的高温下制备了陶瓷。对于重量比为35/26/9/5/25的EVA / GD / GF / OMMT / MCA系统,在800摄氏度形成的陶瓷的弯曲强度为13.82 MPa,UL-94 V-评级为0,LOI为28.2%。而且,CC结果证实,与纯EVA或EVA的相应值相比,复合材料的放热率(HRR),总释放率(THR),冒烟率(SPR)和质量损失率(MLR)显着降低。不含MCA的可陶瓷化EVA复合材料。膨胀计实验分析,SEM和粘度分析表明,由GD和GF形成的低共熔混合物导致高温下形成陶瓷。热重分析(TG)等表明,大量不燃性气体的释放和OMMT的存在均导致EVA / GD / GF / OMMT / MCA的阻燃性比纯EVA好得多或没有MCA的陶瓷化EVA复合材料。

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