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Novel process for biodiesel by reactive absorption

机译:反应吸收生物柴油的新工艺

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Process integration and intensification is increasingly applied also in the biodiesel production, as shown by recent research papers. This study takes previous work on reactive separation processes for biodiesel production to a new level by proposing an innovative technology based on reactive absorption using solid acid catalysts. This is a major step forward since reactive absorption offers significant benefits over reactive distillation, such as: reduced capital investment and operating costs due to the absence of the reboiler and condenser, higher conversion and selectivity as no products are recycled in the form of reflux or boil-up vapors, as well as no occurrence of thermal degradation of the products due to a lower temperature profile in the column. Rigorous simulations embedding experimental results were performed in AspenTech AspenONE engineering suite to design this novel reactive absorption process and evaluate the technical and economical feasibility. The main results are given for a plant producing 10 ktpy biodiesel from waste vegetable oil with high free fatty acids content, using solid acids as green catalysts. This innovative process eliminates all conventional catalyst-related operations, and efficiently uses the raw materials and the reactor volume in an integrated setup that allows significant savings in CapEx and OpEx of the plant.
机译:如最近的研究论文所示,过程集成和强化也越来越多地应用于生物柴油生产中。这项研究通过提出一种基于使用固体酸催化剂的反应吸收的创新技术,将生物柴油生产的反应分离工艺的先前工作提高到了一个新的水平。这是向前迈出的重要一步,因为反应吸收比反应蒸馏具有明显优势,例如:由于没有再沸器和冷凝器,减少了投资和运营成本,由于没有产品以回流或再循环的形式循环使用,因此转化率和选择性更高沸腾的蒸汽,以及由于塔中较低的温度曲线而不会发生产物的热降解。在AspenTech AspenONE工程套件中进行了严格的模拟嵌入实验结果,以设计这种新颖的反应吸收工艺并评估技术和经济可行性。给出了使用固体酸作为绿色催化剂,从具有高游离脂肪酸含量的废植物油中生产10 ktpy生物柴油的工厂的主要结果。这种创新的工艺消除了所有常规的与催化剂相关的操作,并在集成设置中有效地使用了原材料和反应器体积,从而大大节省了工厂的资本支出和运营支出。

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