A new terbium coordination polymer constructed from 4-Oxo-1(4H) quinolineacetate: Synthesis, crystal structure, and fluorescent properties

Wang J.; Hou Y.; Zhuang X.

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A new terbium coordination polymer constructed from 4-Oxo-1(4H) quinolineacetate: Synthesis, crystal structure, and fluorescent properties

机译：一种由4-Oxo-1（4H）喹啉乙酸酯构成的新型ter配位聚合物：合成，晶体结构和荧光性质

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A new terbium complex, Tb(L)_2·2H_2O [L = 4-oxo-1(4H)quinolineacetate] (1), has been synthesized and structurally characterized by elemental analysis, thermal analysis, and infraredspectroscopy, as well as single-crystal X-ray diffraction. Single-crystal X-ray analysis reveals that 1 is a three-dimensional supramolecular network built up from two-dimensional (2D) layers with the (4,4) net that is assembled via hydrogen bonding and ππ stacking interactions. Furthermore, the solid-state photofluorescent property of complex 1 has also been investigated.

机译：合成了一种新的T络合物Tb（L）_2·2H_2O [L = 4-oxo-1（4H）quinolineacetate]（1），并通过元素分析，热分析和红外光谱以及单-晶体X射线衍射。单晶X射线分析揭示1是一个三维二维超分子网络，由二维（2D）层和（4,4）网构成，该网通过氢键和ππ堆积相互作用组装而成。此外，还研究了配合物1的固态光致荧光性质。

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《Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry》 |2011年第7期|共5页
作者
Wang J.; Hou Y.; Zhuang X.;
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正文语种 eng
中图分类化学反应的机理和动力学;
关键词
4-oxo-1(4H)quinolineacetate; crystal structure; fluorescence; H-bonding and π-π stacking interactions;

机译：4-氧代-1（4H）喹啉乙酸酯;晶体结构;荧光;H键和π-π堆积相互作用;

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1. A New Terbium Coordination Polymer Constructed from 4-Oxo-1(4H)quinolineacetate: Synthesis, Crystal Structure, and Fluorescent Properties [J] . Jun Wang, Xiaomei Zhuang Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry . 2011,第7期

机译：一种由4-Oxo-1（4H）喹啉乙酸酯构成的新型Ter配位聚合物：合成，晶体结构和荧光性质
2. Synthesis, crystal structures and photoluminescent properties of lanthanide supramolecular complexes with 4-oxo-1(4H)-quinolineacetate [J] . Wang J, Fan J, Guo LY, Journal of Solid State Chemistry . 2010,第3期

机译：4-氧代-1（4H）-喹啉乙酸酯镧系元素超分子配合物的合成，晶体结构和光致发光性能
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A new terbium coordination polymer constructed from 4-Oxo-1(4H) quinolineacetate: Synthesis, crystal structure, and fluorescent properties

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