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Equation of state of the hard sphere gas

机译:硬球气体的状态方程

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摘要

It is well known that the Enskog factor for the mean free path of the hard sphere gas also quantifies the deviation of the equation of state from that of the ideal gas. We verify this result in a computer simulation by measuring the pressure of the hard sphere gas in the microcanonical ensemble and comparing with mean free paths obtained in all earlier paper. Surprisingly, the pressure is higher than would be expected from the mean free path alone by a factor which depends not only on the size of the container but also on its shape.
机译:众所周知,硬球气体的平均自由程的Enskog因子也可以量化状态方程与理想气体之间的偏差。我们通过测量微规范集合中硬球气体的压力并与所有较早论文中获得的平均自由程进行比较,在计算机仿真中验证了此结果。令人惊讶地,压力比单独的平均自由路径所预期的压力高一个因素,该因素不仅取决于容器的尺寸,还取决于其形状。

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