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Electrochemistry of Sulfur Adlayers on Ag(111). Evidence for a Concentration- andPotential-Dependent Surface-Phase Transition

机译:ag(111)上硫磺层的电化学。浓度和势能相关的表面相变的证据

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The electrochemical deposition of sulfur adlayers on highly-oriented, thin-filmAg( 111) electrodes in aqueous solutions (pH = 13) containing-sodium sulfide, Na2S, is reported. Three voltammetric waves, corresponding to the stepwise formation of a sulfur adlayer, are observed at potentials negative of that necessary to induce bulk oxidation of Ag. The total charge obtained by

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