Poly(Monophosphazophosphazenes) New Polymers with N=PR3

机译：聚（单磷腈膦）新聚合物，N = pR3

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Phosphazene high polymers with N=PR3 (phosphazo) side groups are of interest fromboth the theoretical and potential technological points of view. High polymeric monophosphazophosphazenes were prepared with trifluoroethoxy, phenoxy, anilino, and propylamino side groups. Small-molecule cyclic counterparts were also synthesized as model systems for the macromolecular reactions. These compounds were prepared using both (trichlorophosphazo) pentachlorocyclotriphosphazene (N3P3Cl5NPCl3) and (trichlorophosphazo) pentafluorocyclotriphosphazene (N3P3F5NPCl3) as the starting materials. Specifically, the synthesis of monophosphazophosphazene polymers through the thermal ring-opening polymerization of N3P3Cl5NPCl3 at 150-180 deg C or of N3P3F5NPCl3 at 200-210 deg C is reported.

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Allcock, H. R.; Kuharcik, S. E.; Morrissey, C. T.; Ngo, D. C.;
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年度 1994
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总页数 10
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Polymers; Phosphazene; Thermal properties; Reprints; Models; Synthesis; Polymerization; Reactivities; Sodium; Fluorine; Chemical reactions; Replacement; Macromolecules; Organic radicals; Chlorine; Halogens;

机译：聚合物;磷腈;热性能;重印;模型;合成;聚合;反应活性;钠;氟;化学反应;替代;大分子;有机基团;氯;卤素;

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2. Aminoalkyl-substituted indenylnickel(II) complexes (eta(3):eta(0)-Ind(CH2)(2)NMe2)Ni(PR3)X and[(eta(3):eta(1)-Ind(CH2) 2NMe2)Ni(PR3)][BPh4]: Influence of the phosphine in ligand exchange and polymerization reactions [J] . Groux LF., Zargarian D. Organometallics . 2003,第23期

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3. Protection and polymerization of functional monomers. 29. Syntheses of well-defined poly[(4-vinylphenyl)acetic acid], poly[3-(4-vinylphenyl)propionic acid], and poly(3-vinylbenzoic acid) by means of anionic living polymerizations of protected monomer [J] . Ishizone Takashi, Hirao Akira, Nakahama Seiichi, Macromolecules . 1999,第5期

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5. Development of high-performance polymeric materials: Poly(paraphenylene)s, poly(arylene ether ketone)s and quasicrystal-polymer composites. [D] . Bloom, Paul David. 2001

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8. Preparation of a Polymeric Precursor to Silicon Carbide via Ring-Opening Polymerization: Synthesis of Poly(methylchorosilylene)methylene and Poly(silapropylene). [R] . Wu, H. J., Interrante, L. V. 1989

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Poly(Monophosphazophosphazenes) New Polymers with N=PR3

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