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Preparation and Characterization of Group 14 Element Bis(Thiolate) Compounds andEvaluation of their Potential as Molecular Precursors in the Low Temperature Syntheses of Binary Metal Sulfides

机译:第14族元素双(硫醇盐)化合物的制备和表征及其在二元金属硫化物低温合成中作为分子前体的潜力评价

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Three isomeric lead bis(butylthiolate) and tin bis(butylthiolate) compounds havebeen prepared and characterized. Their solid state decomposition, and in the case of the lead bis(thiolate) compounds, their thermolyses in suspension in a high boiling hydrocarbon, have been studied. X-ray powder diffraction patterns and scanning electron micrographs of the obtained solid state materials are discussed. Volatile co-products of the decomposition have been isolated and characterized.

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