• 主题
高级搜索  >
历史搜索 清空历史
首页> 美国政府科技报告 >Surface-Enhanced Raman Spectroscopy of Electroactive Films of C60 and an Ir-C60Complex on Gold: Symmetry Lowering, Electron Localization, and Counteraction Effects
【24h】

Surface-Enhanced Raman Spectroscopy of Electroactive Films of C60 and an Ir-C60Complex on Gold: Symmetry Lowering, Electron Localization, and Counteraction Effects

机译：C60和Ir-C60复合物在金上的电活性薄膜的表面增强拉曼光谱：对称性降低，电子定位和反作用

获取原文
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Surface-enhanced Raman (SER) spectra are reported for thin films of C60 and (eta5-C9H7)Ir(CO)(eta2-C60) on gold electrodes in acetonitrile. The latter spectra display the hallmarks of vibrational symmetry lowering for C60 arising from metal coordination, involving splitting of the normally degenerate H (sub g) modes and the appearance of vibrationally forbidden bands. Only a milder selection rule relaxation is observed for SERS of uncoordinated C60. Electroreduction of both C60 and the Ir-C60 complex yielded similar frequency downshifts in the Ag pentagonal pinch mode, indicating that electron addition to the latter is fullerene localized. These spectral shifts are sensitive to the nature of the countercation.

著录项

相似文献

  • 外文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号