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Experimental Methods for Probing Structure and Dynamics of Gas-Phase MolecularDications

机译:探讨气相分子结构和动力学的实验方法

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Coaxial ion-laser beam photofragmentation spectroscopy combined with coincidencedetection is a powerful method for probing doubly charged molecular ions. The high-resolution photofragmentation spectra contain detailed information on the molecular structure and dissociation dynamics of doubly charged cations. Our study on N2(2+) reveals detailed intramolecular interactions with other states, and also provides direct information on previously unobserved electronic states of this dication. We discuss these intramolecular interactions and the dissociation mechanism and demonstrate the high sensitivity of this technique.

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