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Fast Ion Conductors as Oxidation Catalysis: Oxidative Coupling and Deep Oxidationof Methane Over Transition Metal Exchanged Beta-Alumina. (Reannouncement with New Availability Information)

机译：快速离子导体作为氧化催化剂：过渡金属交换β-氧化铝上的甲烷氧化偶联和深度氧化。（重新公布新的可用性信息）

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The first catalysis studies using the fast ion conductors, transition-metal-exchanged Beta -Aluminas, are reported. Several new and previously reported materials have been prepared and characterized, and their activity for CH4 Oxidation has been investigated. The Mn(II), Fe(II). and Fe(III) isomorphs are very active for deep oxidation between 300 and 700 deg C, and above 700 deg C oxidative coupling is also observed. The Fe system has been further studied by 57Fe Mossbauer spectroscopy. Both the stoichiometry and the Mossbauer spectroscopy indicate that oxidation of methane involves reduction of Fe(III) to Fe(II).

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作者
Fowles, E. H.; Labinger, J. A.; Beauchamp, J. L.; Fultz, B.;
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年度 1991
页码
总页数 10
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Catalysis; Ions; Oxidation; Conductivity; Catalysts; Metals; Methane; Reduction; Spectroscopy; Transition metals; Reprints; Manganese; Iron; Hydrocarbons; Temperature;

机译：催化;离子;氧化;电导率;催化剂;金属;甲烷;还原;光谱学;过渡金属;重印;锰;铁;碳氢化合物;温度;

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机译：在金属交换的沸石中发现新的甲烷氧化（NEMO）位点：CU-MOR中甲烷的串联氧化和羰基化成乙酸的启示
3. Thermodynamics of Water-Cationic Species-Framework Guest- Host Interactions within Transition Metal Ion-Exchanged Mordenite Relevant to Selective Anaerobic Oxidation of Methane to Methanol [J] . Zhang Xianghui, Cockreham Cody B., Huang Zhiyang, Journal of physical chemistry letters . 2020,第12期

机译：水阳离子物种框架的热力学 - 过渡金属离子交换的甲状腺素内的宿主相互作用，与选择性厌氧氧化甲烷氧化甲醇
4. FINDING NEW METHANE OXIDATION (NEMO) SITES IN METAL-EXCHANGED ZEOLITES: INSIGHTS FROM THE TANDEM OXIDATION AND CARBONYLATION OF METHANE TO ACETIC ACID IN CU-MOR [C] . Karthik Narsimhan, Vladimir K. Michaelis, Guinevere Mathies Joint Conference on Chemisty . 2016

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机译：2H-咪唑1-氧化物与碳硼烷基锂的无过渡金属氧化和脱氧C–H / C–Li交叉偶联是氮杂杂环碳硼烷的有效合成方法
7. Thermodynamics of WaterCationic SpeciesFramework GuestHost Interactions within Transition Metal Ion-Exchanged Mordenite Relevant to Selective Anaerobic Oxidation of Methane to Methanol [O] . -1

机译：用于过渡金属离子交换的甲酸甲烷与甲醇的选择性厌氧氧化内的过渡金属离子交换丝烯岩中的普拉斯特·普拉斯特的热力学

Fast Ion Conductors as Oxidation Catalysis: Oxidative Coupling and Deep Oxidationof Methane Over Transition Metal Exchanged Beta-Alumina. (Reannouncement with New Availability Information)

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