首页> 美国政府科技报告 >Dependence of the Log K Values for the Interaction of Chiral Dimethylpyridino-18-Crown-6 with Alpha-(1-Naphthylethyl) Ammonium Perchlorate on Several Solvent Parameters.

【24h】

Dependence of the Log K Values for the Interaction of Chiral Dimethylpyridino-18-Crown-6 with Alpha-(1-Naphthylethyl) Ammonium Perchlorate on Several Solvent Parameters.

机译：手性二甲基吡啶-18-冠-6与α-（1-萘乙基）高氯酸铵相互作用的Log K值对几种溶剂参数的依赖性。

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

No abstract available.

著录项

作者
Zhu, C. Y.; Izatt, R. M.; Bradshaw, J. S.;
展开▼
作者单位

展开▼
年度 1991
页码 1-2
总页数 2
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Ethers; Complex compounds; Solvents; Chemical equilibrium; Ammonium perchlorate; Chemical reactions; Methyl radicals; Pyridines; Naphthalenes; Ethyl radicals; Nuclear magnetic resonance; Ligands; Constants; Chiral compounds; Crowreb/dimethylpyridino-18; Ammonium perchlorate/(Naphthylethyl); Synthesis(Chemistry); Crown ethers;

机译：醚;络合物;溶剂;化学平衡;高氯酸铵;化学反应;甲基;吡啶;萘;乙基;核磁共振;配体;常数;手性化合物; Crowreb /二甲基吡啶基-18;高氯酸铵/（萘基乙基）;合成（化学）;冠醚;

相似文献

外文文献
专利

1. Chromatographic enantioseparation of racemic #alpha#-(1-naphthyl)-ethylammonium perchlorate by a Merrifield resin-bound enantiomerically pure chiral dimethylpyridino-18-crown-6 ligand [J] . Gyorgy Horvath, Peter Huszthy Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 1999,第23期

机译：通过Merrifield树脂结合的对映体纯对映体纯的手性二甲基吡啶基18-冠6配体进行外消旋#alpha＃-（1-萘基）-乙基氯化铵的色谱对映体分离
2. Solvent-Solvent Cooling Crystallization: An Effective Method to Control the Morphology and Size of Ammonium Perchlorate Crystals [J] . Liu Wei, Xie Yong, Xie Qiang, Crystal Research and Technology: Journal of Experimental and Industrial Crystallography . 2019,第10期

机译：溶剂 - 溶剂冷却结晶：一种控制氯酸铵晶体形态和尺寸的有效方法
3. Generalized solvent scales as a tool for investigating solvent dependence of spectroscopic and kinetic parameters. Application to fluorescent BODIPY dyes [J] . Aleksander Filarowski, Malgorzata Kluba, Katarzyna Cieslik-Boczula Photochemical & photobiological sciences: the official journal of the European Photochemistry Association and the European Society for Photobiology . 2010,第7期

机译：通用溶剂刻度作为研究光谱和动力学参数的溶剂依赖性的工具。应用于荧光BODIPY染料
4. Burning Rate Dependence of Composite Propellants on Ammonium Perchlorate Particle Size [C] . Muhammad Mazhar IQBAL, Sajid RAZA Ch International Seminar on Propellants, Explosives and Pyrotechnics . 2007

机译：复合推进剂对高氯酸铵粒径的燃烧率依赖性
5. Crown ether-cation interactions: Thermodynamic, kinetic, structural, and separation studies. 1.~Chiral and nonchiral interactions of crown ethers with organic ammonium cations. 2.~Macrocycle-mediated membrane separation of europium(II) from lanthanum(III) cations in aqueous solution. [D] . Zhu, Chengyue. 1990

机译：冠醚阳离子相互作用：热力学，动力学，结构和分离研究。 1.〜冠醚与有机铵阳离子的手性和非手性相互作用2.〜大环介导的水溶液中。（III）与镧（III）阳离子的膜分离。
6. Complexation of chiral amines by resorcin4arene sulfonic acids in polar media – circular dichroism and diffusion studies of chirality transfer and solvent dependence [O] . Bartosz Setner, Agnieszka Szumna 2019

机译：间苯二酚4芳烃磺酸在极性介质中的手性胺络合-圆二色性和手性转移和溶剂依赖性的扩散研究
7. Figure 1: Example of visualization of long range contacts for: (A) regions, here enhancer-promoter contacts, for two 10 kb resolution Hi-C maps from human Fetal Brain cells. Contacts were calculated up to 30 bins distance each way from the point of interest. Top to bottom: a Jbrowse (Skinner et al., 2009) screenshot with genes and interaction profile representation (points of interest in green, their contact predictions in yellow); HiCEnterprise interaction profile plot with intensities (weighted by distance) and −log10 of FDR corrected p-values (q-values) with a threshold set at 0.01. (B) TADs, here HiCEnterprise visualization for 150 kb resolution Hi-C map of 17th chromosome from HUVEC. Left upper trianle: original Hi-C map contact frequencies; right lower triangle: −log10 of q-values of the interdomain interactions calculated with hypergeometric distribution. [O] . -1

机译：图1：用于：（a）区域的长距离触点的可视化示例，这里增强了来自人胎儿脑细胞的两个10kb分辨率的Hi-C地图。从兴趣点计算联系人高达30个距离距离。顶部到底：jbrowse（Skinner等，2009）截图，具有基因和互动曲线表示（绿色兴趣点，它们的黄色接触预测）; HICENTERPLISE交互配置曲线图具有强度（由距离加权）和FDR校正的P值（Q值）的-LOG10，其阈值设置为0.01。（b）TADS，这里是来自Huvec的第17次染色体的150 KB分辨率Hi-C地图的Hicenterprise可视化。左上三角：原版Hi-C地图接触频率;右下三角形：跨度相互作用的Q值的-log10计算，使用超几何分布计算。
8. Recognition by New Symmetrically Substituted Chiral Diphenyl-and Di-tert-butylpyridino-18-crown-6 and Asymmetrically Substituted Chiral Dimethylpyridino-18-crown-6 Ligands of the Enantiomers of Various Organic Ammonium Perchlorates [R] . Huszthy, P., Bradshaw, J. S., Zhu, C. Y., 1991

机译：通过新的对称取代的手性二苯基 - 和二 - 叔丁基吡啶基-18-冠-6和不对称取代的手性二甲基吡啶基-18-冠-6配体的各种有机高氯酸铵对映体的识别

Dependence of the Log K Values for the Interaction of Chiral Dimethylpyridino-18-Crown-6 with Alpha-(1-Naphthylethyl) Ammonium Perchlorate on Several Solvent Parameters.

摘要

著录项

相似文献

相关主题

期刊订阅