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首页> 美国政府科技报告 >Structural Synergism in Functionalized Polymers: New Catalysts for TransacylationReactions of Derivatives of Carboxylic and Phosphoric Acids
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Structural Synergism in Functionalized Polymers: New Catalysts for TransacylationReactions of Derivatives of Carboxylic and Phosphoric Acids

机译：功能化聚合物中的结构协同作用：羧酸和磷酸衍生物的反式酰化反应的新催化剂

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This project has focused on the development of new highly-efficient, selectivecatalysts for widely commercial and biological reactions of carboxylic and phophoric acids and their derivatives. The first phase of the project included the design and synthesis of linear, water-soluble polymers that are expected to self organize in aqueous solution to form lipophilic substrate-binding domains adjacent to catalytic sites effective in transacylation reactions. The second phase of this work has dealt with the continuing evaluation of synthetic catalysts and the development of new methods for detailed structural characterization of these polymeric materials. The ultimate aim of this phase of the investigation is to ascertain the limits of substrate-selectivity for linear, synthetic polymeric catalysts.

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