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Facile Synthesis for Functional Perfluoropolyether Oligomers, Diacids, Diesters,and Surfactants

机译：功能性全氟聚醚低聚物，二酸，二酯和表面活性剂的简便合成

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摘要

Linear polyester precursors provide a convenient low cost synthesis forfluorocarbon surfactants, diacids, diesters, and intermediates. A reaction scheme starting with hydrocarbon linear polyesters followed by conversion of the ester to a perfluoro ester by direct fluorination and subsequent treatment with nonstoichiometric amounts of sulfur tetrafluoride produce upon hydrolysis of ester units, remaining in the polymer, low molecular weight perfluoropolyether diacids. Alternatively, this technique can be altered slightly to produce diesters and other functional perfluorocarbon intermediates.

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作者
Persico, D. F.; Lagow, R. J.;
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年度 1991
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总页数 11
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Conversion; Esters; Ethers; Fluorides; Fluorinated hydrocarbons; Fluorination; Fluoropolymers; Hydrocarbons; Hydrolysis; Low costs; Oligomers; Polyester fibers; Polyester plastics; Precursors; Response; Starting; Sulfur; Surface active substances; Synthes;

机译：转化;酯类;醚类;氟化物;氟化烃;氟化;含氟聚合物;碳氢化合物;水解;低成本;低聚物;聚酯纤维;聚酯塑料;前体;响应;起始;硫;表面活性物质;合成;

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1. Phthalonitrile-functionalized poly(ether imide) oligomers derived from phthalazinone-containing dianhydride: facile synthesis, curing and properties [J] . Liu Cheng, Lin Encheng, Zong Lishuai, Polymer bulletin . 2018,第3期

机译：磷脂腈官能化聚（醚酰亚胺）含有含酞啶的二酐的低聚物：容易合成，固化性和性能
2. Facile one-pot synthesis of different surfactant-functionalized water-soluble Fe3O4 nanoparticles as magnetic resonance imaging contrast agents for melanoma tumors [J] . Wu Longyun, Yang ChunYan, Lv Zhongwen, RSC Advances . 2015,第62期

机译：不同表面活性剂官能化水溶性Fe3O4纳米粒子的孔瘤肿瘤的磁共振成像对比剂
3. Facile synthesis of functionalized ionic surfactant templated mesoporous silica for incorporation of poorly water-soluble drug [J] . Li Jing, Xu Lu, Yang Baixue, International Journal of Pharmaceutics . 2015,第1a2期

机译：易于合成功能性离子表面活性剂模板化介孔二氧化硅，以掺入水溶性差的药物
4. Optimizing the Acid Catalyzed Synthesis of Hyperbranched Poly(glycerol-diacid) Oligomers [C] . Victor T. Wyatt, Alberto Nunez, Thomas A. Foglia PMSE Symposia . 2007

机译：优化超支化聚（甘油 - 二酸）低聚物的酸催化合成
5. Part I. Asymmetric synthesis of bicyclic analogues of risedronate as molecular probes of the mechanism of action of bisphosphonate antiosteoporotic drugs and potentially more efficacious antiosteoporotic agents. Part II. Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using the Bestmann ylide and their use in Wittig reactions. Part III. Asymmetric organocatalysis: 1. An investigation of alpha-hydroxylation of aldehydes; 2. Synthesis of a novel camphor-based alpha-aminotetrazole organocatalyst. [D] . Song, Xinyi. 2007

机译：第一部分：利塞膦酸盐双环类似物的不对称合成，作为双膦酸盐类抗骨质疏松药和潜在更有效的抗骨质疏松药作用机理的分子探针。第二部分使用Bestmann内酯从常见手性助剂轻松制备和官能化手性稳定化的叶基及其在Wittig反应中的用途。第三部分不对称有机催化：1.醛的α-羟基化研究； 2.合成新的基于樟脑的α-氨基四唑有机催化剂。
6. Itaconic Acid Based Surfactants: I. Synthesis and Characterization of Sodium n-Octyl Sulfoitaconate Diester Anionic Surfactant [O] . Jun Xu, Fengzhi Cao, Tong Li, -1

机译：基于衣康酸的表面活性剂：I.辛基磺基乙酸正辛酯二酯阴离子表面活性剂的合成与表征
7. Tris(2-methoxyphenyl)bismuthane as a Dehydrating Agent with High Template Ability: an Efficient Single-step Synthesis of Macrocyclic Diesters from Diacid Anhydrides and Glycols [O] . Ogawa Takuji, Yoshikawa Akemi, Wada Hidemi, 2017

机译：三（2-甲氧基苯基）铋作为具有高模板能力的脱水剂：由二酸酐和乙二醇高效一步合成大环二酯
8. Routes to Functionalized Guanidines. The Synthesis of Guanidino Diesters. [R] . Bosin, T. R., Hanson, R. N., Rodricks, J. V., 1972

机译：路线到功能化的胍类。胍基二酯的合成。

Facile Synthesis for Functional Perfluoropolyether Oligomers, Diacids, Diesters,and Surfactants

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