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Miscibility in Poly-p-Phenylene Terephthalamide/Nylon 6 and Nylon 66 Molecular Composites

机译:聚对苯二甲酰对苯二胺/尼龙6和尼龙66分子复合材料的混溶性

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Miscibility and crystallization of poly-p-phenylene terephthalamide (PPTA)/nylon 6 and nylon 66 composites prepared by coagulation of isotropic ternary sulfuric acid solutions were studied. The apparent crystallinity of nylon 6 and nylon 66 in molecular composites was investigated by differential scanning calorimetry and Fourier transform infrared spectroscopy. The solvation of nylon 6 crystals in PPTA matrix was observed when the PPTA content exceeds 70 wt%. Cross-hydrogen bonding seems to be responsible for the virtual disappearance of nylon 6 crystals. Specific interaction between PPTA and nylon 6 macromolecules and phase separation during thermal treatment has been discussed. Reprints. (AW)

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