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Catalytic Hydrolysis of p-Nitrophenyldiphenyl Phosphate in a CTAB (Cetyltrimethylammonium Bromide) Microemulsion

机译：CTaB（十六烷基三甲基溴化铵）微乳液催化水解对硝基苯基二苯基磷酸酯

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The iodosobenzoate catalysis of the hydrolysis of p-nitrophenyldiphenyl phosphate in an oil-in-water microemulsion stabilized by cetyltrimethylammonium bromide and 1-butanol has been examined. In addition, we have investigated this hydrolysis in water and in cetyltrimethylammonium chloride micellar solutions. The second-order rate constants for the catalytic and non-catalytic pathways have been determined. Direct tests demonstrate that iodosobenzoate is a turnover catalyst. (aw)

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作者
Mackay, R. A.; Durst, H. D.; Longo, F. R.; Knier, B. L.;
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年度 1989
页码 p.1-18
总页数 18
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Catalysis; Hydrolysis; Organophosphates; Catalysts; Test and evaluation; Water; Reaction kinetics; Constants; Nitro radicals; Phenyl radicals; Benzoates;

机译：催化;水解;有机磷酸盐;催化剂;测试和评价;水;反应动力学;常数;硝基自由基;苯基自由基;苯甲酸酯;

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2. CATALYTIC ACTIVITY OF CETYLTRIMETHYLAMMONIUM BROMIDE (CTAB) IN THE REACTION OF NINHYDRIN AND ZINC GLYCYLTYROSINE COMPLEX [J] . Mohd. Akram, Dileep Kumar, Kabir-ud-Din European Chemical Bulletin . 2013,第10期

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3. Factors Determining the Catalytic Activity of the Mixed Micellar System Cetyltrimethylammonium Bromide-Brij-35 in the Hydrolysis of a Phosphonic Acid Ester [J] . L. Ya. Zakharova, F. G. Valeeva, A. R. Ibragimova, Kinetics and catalysis . 2012,第3期

机译：确定混合胶束体系十六烷基三甲基溴化铵-Brij-35在磷酸酯水解中的催化活性的因素
4. Development And Characterization Of Materials Sensitive To Dopamine, DP, Concentration. Influence Of Cetyltrimethylammonium Bromide, CTAB [C] . L. Hernandez Martinez, M. T. Ramirez Silva, G. A. Rosquete Pina, Meeting of the Electrochemical Society . 2007

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5. Developing artificial proteases and nucleases: Catalytic hydrolysis of unactivated amides, nitriles and phosphates. Part~I. Hydrolysis of phosphate esters promoted by cobalt(III) complexes. Part~II. Hydration of nitriles catalyzed by cobalt(III) complexes. Part~III. Hydrolysis of amides promoted by cobalt(III) complexes. [D] . Kim, Jung Hee. 1992

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6. Cetyltrimethylammonium Bromide (CTAB)-Loaded SiO [O] . Aiganym Abduraimova, Anara Molkenova, Assem Duisembekova, 2021

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7. Investigating cetyltrimethylammonium bromide (CTAB) reverse microemulsions using nuclear magnetic resonance [O] . Mills Amanda Jayne 2016

机译：用核磁共振研究十六烷基三甲基溴化铵（CTaB）反相微乳液

Catalytic Hydrolysis of p-Nitrophenyldiphenyl Phosphate in a CTAB (Cetyltrimethylammonium Bromide) Microemulsion

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