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Electrochemical Oxidation of Some Metal Carbonyls in Ambient Temperature Ionic Liquids.

机译：环境温度离子液体中某些金属羰基化合物的电化学氧化。

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The electrochemical oxidation of Cr(C0)6, W(C0)6 and Fe(C0)5 was studied in the AlCl3:N(1-butyl)pyridinium chloride (BuPyCl) molten salt at 40 C. In the 1:1 to 2:1 mole ratio of AlCl3/BuPyClk,Cr(C0)6 was found to be reversibly oxidized forming stable Cr(C0)+6. Further oxidation of Cr(C0)(6)+ generated Cr(C0)6 (3+) which was not stable. Iron pentacarbonyl and tungsten hexacarbonyl in 1:1 to 2:1 melts each showed a single oxidation with some stability of their cations. Fe(C0)(5)+ was more stable than W(CO)6(2+). In the melt of <1:1 mole ratio no evidence was found for the formation of stable Fe(C0)(5)+.

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作者
Sahami, S.; Osteryoung, R. A.;
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年度 1985
页码 1-6
总页数 6
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Electrochemistry; Oxidation; Carbonyl compounds; Fused salts; Aluminum compounds; Chlorides; Stability; Chromium; Tungsten; Iron; Cations; Voltammetry; Reprints;

机译：电化学;氧化;羰基化合物;熔融盐;铝化合物;氯化物;稳定性;铬;钨;铁;阳离子;伏安法;重印;

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8. Electrochemical Oxidation of Some Metal Carbonyls in Ambient Temperature Ionic Liquids [R] . Sahami, S., Osteryoung, R. A. 1985

机译：环境温度离子液体中某些金属羰基化合物的电化学氧化

Electrochemical Oxidation of Some Metal Carbonyls in Ambient Temperature Ionic Liquids.

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