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Charging and Discharging Rate Studies of Polypyrrole Films in AlCl3:1-Methyl-(3-Ethyl)-Imidazolium Chloride Molten Salts and in CH3CN

机译：alCl3：1-甲基 - （3-乙基） - 咪唑氯化物熔盐和CH3CN中聚吡咯薄膜的充放电速率研究

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The chronocoulometric charging and discharging of polypyrrole films in basic Aluminum Chloride/1-methyl-(3-ethyl)-imidazolium chloride molten salts and Acetonitrile have been investigated. Both processes follow a t sub 1/2 time dependence and are significantly faster in the molten salts. Comparison with redox polymer and porous electrode models shows that neither model is satisfactorily applicable over the entire potential region studied. The charging and discharging rates are limited by ion migration in the polymer and for potential steps in the double layer charging region polypyrrole behaves as a porous electrode material. In this region there is good correlation between the charging /discharging rates and the solvent conductivity. Keywords: Electroactive polymers; Chloroaluminate molten salts.

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Pickup, P. G.; Osteryoung, R. A.;
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年度 1985
页码 p.1-19
总页数 19
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Aluminates; Pyrroles; Polymers; Acetonitrile; Electrocatalysts; Fused salts; Electrodes; Porous materials; Rates; Conductivity; Solvents; Ions; Migration; Films; Models; Oxidation reduction reactions; Reprints;

机译：铝酸盐;吡咯;聚合物;乙腈;电催化剂;熔融盐;电极;多孔材料;速率;电导率;溶剂;离子;迁移;薄膜;模型;氧化还原反应;重印;

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专利

1. Acidity of neutral buffered 1-ethyl-3-methylimidazolium chloride AlCl3 ambient-temperature molten salts [J] . Koronaios P., Osteryoung RA., King D. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第8期

机译：中性缓冲1-乙基-3-甲基咪唑氯化铝AlCl3常温熔融盐的酸度
2. Electrochemical Scanning Tunneling Microscopy Investigation of HOPG and Silver Electrodeposition on HOPG from the Acid Room-Temperature Molten Salt Aluminum Chloride-1-Methyl-3-butyl-imidazolium Chloride [J] . Frank Endres, Werner Freyland The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 1998,第50期

机译：酸性室温熔融盐氯化铝-1-甲基-3-丁基咪唑鎓氯化物对HOPG的电化学扫描隧道显微镜研究和HOPG上的银电沉积
3. Electrochemical Scanning Tunneling Microscopy Investigation of HOPG and Silver Electrodeposition on HOPG from the Acid Room-Temperature Molten Salt Aluminum Chloride- 1-Methyl-3-buty -imidazolium Chloride [J] . Frank Endres, Werner Freyland The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 1998,第49a52期

机译：酸性室温熔融盐氯化铝-1-甲基-3-丁基-咪唑鎓氯化物对HOPG的电化学扫描隧道显微镜研究和HOPG上银的电沉积
4. Molten Chloride Salts for Next Generation CSP Plants: Selection of Promising Chloride Salts Study on Corrosion of Alloys in Molten Chloride Salts [C] . Wenjin Ding, Alexander Bonk, Thomas Bauer International Conference on Concentrating Solar Power and Chemical Energy Systems . 2019

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5. The recovery of magnesium oxide and hydrogen chloride from magnesium chloride brines and molten salt hydrates. [D] . de Bakker, Jan Simon Christiaan. 2011

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6. Preparation and Characterization of Regenerated Cellulose Film from a Solution in Lithium Bromide Molten Salt Hydrate [O] . Xueqin Zhang, Naiyu Xiao, Huihui Wang, 2018

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7. Molten chloride salts for next generation CSP plants: Selection of promising chloride salts study on corrosion of alloys in molten chloride salts [O] . Wenjin Ding, Alexander Bonk, Thomas Bauer 2019

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8. Charge Transport in Poly-(Ru(2,2'-Bipyridine)2(4-Vinylpyridine)2)(3+/2) Films in AlCl3/N-(1-Butyl)Pyridinium Chloride and AlCl3/1-Methyl(3-Ethyl)Imidazolium Chloride Molten Salts [R] . Pickup, P. G., Osteryoung, R. A. 1985

机译：聚（Ru（2,2'-联吡啶）2（4-乙烯基吡啶）2）（3 + / 2）膜在alCl3 / N-（1-丁基）吡啶氯化物和alCl3 / 1-甲基（3）中的电荷传输 - 乙基）咪唑氯化物熔盐

Charging and Discharging Rate Studies of Polypyrrole Films in AlCl3:1-Methyl-(3-Ethyl)-Imidazolium Chloride Molten Salts and in CH3CN

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