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Homogeneous Reaction Involving Components of Different Redox Couples. 2. Polarographic Studies of the Interactions of Alkali Metal Cations with Anthracene and Fluoroanthene Dianions in N,N-dimethylformamide and Acetonitrile.

机译：涉及不同氧化还原对偶组分的均相反应。 2.碱金属阳离子与N，N-二甲基甲酰胺和乙腈中的蒽和氟芴二价阳离子相互作用的极谱研究。

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The polarographic behavior of mixtures of anthracene (An), fluoranthene (Fa) and alkali metal cations in N,N-dimethylformamide (DMF) or acetonitrile (ACN) indicates that the electrogenerated dianion of the hydrocarbon reacts with the metal cation in the diffusion layer to form ion complexes. This results, in the case of sodium or lithium cations with anthracene in both DMF and ACN, in the appearance of the invented polarographic waves. In the case of other alkali metal cations (K+, Rb+), the intensity of the polarographic wave due to the reduction to the hydrocarbon dianion is simply decreased. The stoichiometries and mechanisms of the interactions are discussed.

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Khoo, S. B.; Pons, S.; Janata, J.; Feldberg, S.; Foley, J. K.;
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年度 1984
页码 1-35
总页数 35
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Ion ion interactions; Alkali metals; Anthracenes; Hydrocarbons; Polarographic analysis; Oxidation reduction reactions; Coupling(interaction); Cations; Anions; Formamides; Methyl radicals; Acetonitrile; Sodium; Lithium; Potassium; Rubidium; Stoichiometry; Homogeneity; Ion pairing; Fluoranthene; Anthracene; Formamide/N-N-dimethyl;

机译：离子相互作用;碱金属;蒽;碳氢化合物;极谱分析;氧化还原反应;偶联（相互作用）;阳离子;阴离子;甲酰胺;甲基;乙腈;钠;锂;钾;铷;化学计量;均匀性;离子配对;荧蒽;蒽;甲酰胺/ NN二甲基;

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Homogeneous Reaction Involving Components of Different Redox Couples. 2. Polarographic Studies of the Interactions of Alkali Metal Cations with Anthracene and Fluoroanthene Dianions in N,N-dimethylformamide and Acetonitrile.

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