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Synthesis of Alkylphosphazenes Via Copper-Phosphazene Intermediates

机译：铜 - 磷腈中间体合成烷基磷腈

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摘要

A new reaction route has been developed for the synthesis of a hitherto inaccessible series of 1,1-dialkyltetrachlorocyclotriphosphazenes. The high yield route involves the interaction of hexachlorocyclotriphosphazene, (NPCl2)3, with alkyl Grignard reagents in the presence of n-Bu3PCuI4, followed by treatment with alkyl halides. The structural characterization of these compounds by NMR and mass spectrometric techniques is discussed, together with the reaction mechanism.

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作者
Allcock, H. R.; Harris, P. J.; Connolly, M. S.;
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年度 1980
页码 p.1-51
总页数 51
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Synthesis(Chemistry); Phosphazene; Alkyl radicals; Copper compounds; Organometallic compounds; Cyclic compounds; Models; Reaction kinetics; Grignard reagents; Halides; Yield;

机译：合成（化学）;磷腈;烷基;铜化合物;有机金属化合物;环状化合物;模型;反应动力学;格氏试剂;卤化物;产率;

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Synthesis of Alkylphosphazenes Via Copper-Phosphazene Intermediates

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