首页> 美国政府科技报告 >Tetrametallic Nickel-Boron Clusters, (ETA to the 5th power-C5H5)4Ni4B4H4and (ETA to the 5th power-C5H5)4Ni4B5H5,by transition metal aggregation on a small Borane framework.

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Tetrametallic Nickel-Boron Clusters, (ETA to the 5th power-C5H5)4Ni4B4H4and (ETA to the 5th power-C5H5)4Ni4B5H5,by transition metal aggregation on a small Borane framework.

机译：通过在小硼烷骨架上的过渡金属聚集，四元醇镍 - 硼簇（ETa至第五电力-C5H5）4Ni4B4H4和（ETa至第五电力-C5H5）4Ni4B5H5。

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The reaction of Na+B5H8- with nickelocene and sodium amalgam in tetrahydrofuran at ambient temperature yielded the title compounds, which were isolated as crystalline solids and characterized from their B11 and H FT NMR and mass spectra and an X-ray structure determination of the Ni4B4 cluster.

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bowser,james r. grimes,russell n.;
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年度 1978
页码 1-13
总页数 13
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Boranes; Metal complexes; Synthesis(Chemistry); Nickel compounds; Transition metal compounds; Sodium borohydrides; Furans; Crystal structure; Nuclear magnetic resonance; Mass spectra; X ray diffraction; Molecular structure;

机译：硼烷;金属配合物;合成（化学）;镍化合物;过渡金属化合物;硼氢化钠;呋喃;晶体结构;核磁共振;质谱; X射线衍射;分子结构;

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1. Reactivity of the tetrametallic carbido cluster (C5Me5)WOs3(mu(4)-C)(mu-H)(CO)(11) with alkyne: Isomerization of an allyl fragment on a tetrametallic cluster framework and ring-methyl activation in the C5Me5 ligand [J] . Chung C., Chi Y., Peng SM., Organometallics . 1998,第11期

机译：四金属羰基簇（C5Me5）WOs3（mu（4）-C）（mu-H）（CO）（11）与炔的反应性：四金属簇骨架上烯丙基片段的异构化和C5Me5中的环甲基活化配体
2. Robert H. Crabtree The Organometallic Chemistry of the Transition Metals, 5th edn John Wiley and Sons, 2009, 520 pp. (hardback) ISBN 978-0-470-25762-3 [J] . Peter Craig Applied Organometallic Chemistry . 2010,第9期

机译：Robert H. Crabtree，《过渡金属的有机金属化学》，第五版，约翰·威利父子出版社，2009年，520页。（精装本）ISBN 978-0-470-25762-3
3. Boranes, Carboranes, Metalloboranes, Transition Metal Carbonyls and Other Cluster Formulas Obey the Law of Skeletal Numbers and Their Valences [J] . Enos Masheija Rwantale Kiremire American Journal of Chemistry . 2017,第4期

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Tetrametallic Nickel-Boron Clusters, (ETA to the 5th power-C5H5)4Ni4B4H4and (ETA to the 5th power-C5H5)4Ni4B5H5,by transition metal aggregation on a small Borane framework.

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