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Semiconductor Electrodes Photo-Induced Electrogenerated Chemiluminescence and Up-Conversion at Semiconductor Electrodes.

机译:半导体电极光致电生成化学发光和半导体电极上转换。

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A photosensitized reduction process, leading to electrogenerated chemiluminescence (ECL) at a p-type silicon electrode in which neither the energy of the light used for sensitization nor the electrical energy input reach the threshold energy for the production of the emitted photon if applied separately, is described and discussed. The main experiment consisted of irradiating a p-type Si electrode, immersed in an acetonitrile solution containing 9,10-dichloro-9,10-dihydro-9,10-diphenyl anthracene (DPACl2) and held at a potential where DPACl2 reduction does not occur, with light of energy less than 1.7 eV. The photosensitized reduction of DPACl2 leads to the production of excited singlet 9,10-diphenylanthracene and the emission of 3.0 eV light. (Author)

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