首页> 美国政府科技报告 >Investigations of the Recombination of O Atoms with CO over the Largest Range of Temperature and Pressure Practicable in the Shock Tube (1); Study of the Thermal Dissociation of Hydrogen Peroxide at Temperature Above 1000 K (2); Study of the Unimolecular Dissociation of Formaldehyde (3)

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Investigations of the Recombination of O Atoms with CO over the Largest Range of Temperature and Pressure Practicable in the Shock Tube (1); Study of the Thermal Dissociation of Hydrogen Peroxide at Temperature Above 1000 K (2); Study of the Unimolecular Dissociation of Formaldehyde (3)

机译：在冲击管中可实现的最大温度和压力范围内用CO重组O原子的研究（1）;高温1000 K以上过氧化氢热解离的研究（2）;甲醛单分离解离的研究（3）

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The recombination reaction CO+O+M yields CO2+M was studied in incident and reflected shock waves from 1200 K to 2300 K. The recombination rate constant has a slightly negative apparent activation energy and confirms an unusual behaviour of the temperature dependence of the recombination rate constant. The unimolecular dissociation of hydrogen peroxide was investigated near the low pressure limit. Experiments at 20atm indicated the beginning of the fall-off region. In addition, light absorption corresponding to a species which forms and is consumed again during the reaction, was observed around 2300A. This absorption is possibly due to HO2. The thermal dissociation of formaldehyde at low concentrations in argon was investigated at temperatures 1400

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Meyer, E.; Olschewski, H. A.; Schecker, H. G.; Troe, J.; Vasatko, H.;
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年度 1970
页码 p.1-65
总页数 65
原文格式 PDF
正文语种 eng
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关键词
Carbon monoxide ; Recombination reactions ; Hydrogen peroxide ; Pyrolysis ; Formaldehyde ; Dissociation ; Oxygen ; Reaction kinetics ; Chemical equilibrium ; West Germany;

机译：一氧化碳;重组反应;过氧化氢;热解;甲醛;解离;氧;反应动力学;化学平衡;西德;

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1. The thermal dissociation/recombination reaction of hydrogen peroxide H_2O_2(+M) ? 2OH(+M) III. Analysis and representation of the temperature and pressure dependence over wide ranges [J] . J. Troe Combustion and Flame . 2011,第4期

机译：过氧化氢H_2O_2（+ M）2的热解离/重组反应2OH（+ M）III。在宽范围内分析和表示温度和压力的依赖性
2. SACM/CT Study of the dissociation/recombination dynamics of hydrogen peroxide on an ab initio potential energy surface Part II. Specific rate constants k(E,J), thermal rate constants k_∞(T), and lifetime distributions [J] . J. Troe, V. G. Ushakoy Physical chemistry chemical physics: PCCP . 2008,第26期

机译：SACM / CT研究从头算势能表面上过氧化氢的解离/重组动力学第二部分。比速率常数k（E，J），热速率常数k_∞（T）和寿命分布
3. An experimental and theoretical high temperature kinetic study of the thermal unimolecular dissociation of fluoroethane [J] . Binod R. Giri, John. H. Kiefer, Hui Xu Physical chemistry chemical physics: PCCP . 2008,第41期

机译：氟乙烷热单分子解离的实验和理论高温动力学研究
4. A shock tube investigation of H atom production from the thermal dissociation of ortho-benzyne radicals [C] . C. Xu, M. Braun-Unkhoff, C. Naumann, International Symposium on Combustion; 20060805-11; University of Heidelberg(DE) . 2006

机译：冲击管研究邻苯并甲醛自由基热解产生的H原子
5. Amino acids under hydrothermal conditions: Apparent molar volumes, apparent molar heat capacities, and acid /base dissociation constants for aqueous alpha-alanine, beta-alanine, glycine, and proline at temperatures from 25 to 250°C and pressures up to 30.0 MPa. [D] . Clarke, Rodney George Francis. 2000

机译：水热条件下的氨基酸：在25至250°C的温度和最高30.0 MPa的压力下，水性α-丙氨酸，β-丙氨酸，甘氨酸和脯氨酸的表观摩尔体积，表观摩尔热容量和酸/碱解离常数。
6. Pressure dissociation studies provide insight into oligomerization competence of temperature-sensitive folding mutants of P22 tailspike [O] . Brian G. Lefebvre, Noelle K. Comolli, Matthew J. Gage, 2004

机译：压力解离研究提供了对温度敏感的P22尾钉折叠突变体的寡聚能力的见解
7. Shock Tube Study of Thermal Rearrangement of 1, 5-Hexadiyne over Wide Temperature and Pressure Regime [O] . -1

机译：在宽温度和压力方案中，震动管测量的热重排，5-Hexadiyne的研究
8. Studies of the Rare-Earth Hydrides Technical ReportⅢPRESSURE-TEMPERATURE-COMPOSITION STUDIES OF THE LANTHANUM-, CERIUM-, PRASEODYMIUM-, NEODYMIUM-, SAMARIUM-, and YTTERBIUM-HYDROGEN SYSTEMS. RESULTS Results and Discussion of Dissociation Pressure Measurem [R] . James C. Warf, William L. Korst 1956

机译：稀土氢化物技术报告的研究Ⅲ镧 - ，铈 - ，镨 - ，钕 - ，钐 - 和镱 - 氢系统的压缩 - 温度 - 组成研究。结果解离压力测量的结果和讨论

Investigations of the Recombination of O Atoms with CO over the Largest Range of Temperature and Pressure Practicable in the Shock Tube (1); Study of the Thermal Dissociation of Hydrogen Peroxide at Temperature Above 1000 K (2); Study of the Unimolecular Dissociation of Formaldehyde (3)

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