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A Variable-Temperature Nuclear Magnetic Resonance Study of Complexes of Borane and Boron Trihalides with Acetone, Diethyl Ether, Dimethyl Ether, N,N-Dimethylformamide, Methanol, and Tetrahydrofuran.

机译：硼烷和三卤化硼配合物与丙酮，二乙醚，二甲醚，N，N-二甲基甲酰胺，甲醇和四氢呋喃的可变温度核磁共振研究。

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A proton and boron-11 chemical shift and coordination number study of complexes of diborane and the boron trihalides with dimethyl ether, diethyl ether, methanol, tetrahydrofuran, and, to a small extent, acetone and N,N-dimethylformamide has been completed. At low temperatures, separate proton resonance signals are observed for bulk solvent and solvent molecules complexed with the boron species. Coordination numbers were measured by the direct integration of the separate signals. The chemical shift separations for bulk and complexed solvent signals decreased in the order BBr3 > BCl3 > BF3 > BH3. An attempt is made to relate these separations to the coordinating abilities of the boron halides. The proton chemical shift data of the bases were correlated with some diborane 11B and 1H nuclear magnetic resonance results to obtain information concerning the species present in the ether-diborane solution. (Author)

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Fratiello, A.; Onak, T. P.; Schuster, R. E.;
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年度 1968
页码 1-15
总页数 15
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关键词
Complex compounds; Boron compounds; Nuclear magnetic resonance; Diboranes; Fluorides; Chlorides; Bromides; Organic solvents; Ethers; Ethyl ethers; Formamides; Furans; Acetones; Temperature; Boron bromide; Boron chloride; Boron fluoride; Dimethyl formamides; Methyl ethers; Tetrahydro furans;

机译：复合化合物;硼化合物;核磁共振;二硼烷;氟化物;氯化物;溴化物;有机溶剂;醚类;乙醚;甲酰胺;呋喃;丙酮类;温度;溴化硼;氯化硼;氟化硼;二甲基甲酰胺;甲基醚;四氢化萘呋喃;

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机译：路易斯酸催化环氧化物开环的新观点。甲醇，乙酸，二甲醚，乙醚和环氧乙烷与三氟化硼的某些配合物的理论研究
2. Experimental electron-ion dissociative recombination rate constant and temperature dependence data for protonated methanol, ethanol, dimethyl ether and diethyl ether [J] . Lawson Patrick A., Osborne David S. Jr., Adams Nigel G. International journal of mass spectrometry . 2014,第Null期

机译：质子化甲醇，乙醇，二甲醚和乙醚的实验电子离子解离重组速率常数和温度依赖性数据
3. A comparative study on the autoxidation of dimethyl ether (DME) comparison with diethyl ether (DEE) and diisopropyl ether (DIPE) [J] . Michie Naito, Claire Radcliffe, Yuji Wada, Journal of loss prevention in the process industries . 2005,第4a6期

机译：二甲醚（DME）自氧化与二乙醚（DEE）和二异丙醚（DIPE）的比较研究
4. STUDY ON SYNTHESIS OF DIMETHYL CARBONATE BY CO-FEEDING METHANOL AND DIMETHYL ETHER [C] . Chang Yanhong, Yang Caihong, Bai Liang, The 7th China-Japan symposium on coal and C1 chemistry proceedings . 2001

机译：甲醇与二甲醚共进料合成碳酸二甲酯的研究
5. Catalytic and kinetic study of methanol dehydration to dimethyl ether. [D] . Hosseininejad, Seyed Shaham Aldin. 2010

机译：甲醇脱水制二甲醚的催化和动力学研究。
6. Di-μ-acetato-bis(dimethylformamide)pentakis(μ-N2-dioxidobenzene-1-carboximidato)tetrakis(1-ethylimidazole)pentamanganese(III)manganese(II)–diethyl ether–dimethylforamide–methanol–water (1/1/1/1/0.12) [O] . Benjamin R. Tigyer, Matthias Zeller, Curtis M. Zaleski 2011

机译：Di-μ-乙酰基-双（二甲基甲酰胺）五（（N-N2-二氧化苯-1-羧酰亚胺）四（1-乙基咪唑）五锰（II）-二乙醚-二甲基甲酰胺-甲醇-水（1 / 1/1/1 / 0.12）
7. Di-μ-acetato-bis(dimethylformamide)pentakis(μ-N,2-dioxidobenzene-1-carboximidato)tetrakis(1-ethylimidazole)pentamanganese(III)manganese(II)–diethyl ether–dimethylforamide–methanol–water (1/1/1/1/0.12) [O] . Tigyer, Benjamin R., Zeller, Matthias, Zaleski, Curtis M. 2011

机译：二-μ-乙酰基-双（二甲基甲酰胺）五（（N-N，2-二氧化苯-1-羧酰亚胺）四（1-乙基咪唑）五锰（II）-二乙醚-二甲基甲酰胺-甲醇-水（1 / 1/1/1 / 0.12）
8. A Proton Magnetic Resonance Study of Boron Trihalide Complexes with Diethyl Ether [R] . Schuster, R., Fratiello, A., Onak, T. 1967

机译：三卤化硼与二乙醚配合物的质子磁共振研究

A Variable-Temperature Nuclear Magnetic Resonance Study of Complexes of Borane and Boron Trihalides with Acetone, Diethyl Ether, Dimethyl Ether, N,N-Dimethylformamide, Methanol, and Tetrahydrofuran.

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