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Polymers with Conjugated Bonds and Hetero-Atoms in a Conjugated Chain

机译：共轭链中具有共轭键和杂原子的聚合物

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Salicyl derivatives of ferrocene were obtained that were never described before. Polymer chelate complexes were obtained of tetrasalicylates of ferrocene with copper, beryllium, bi- and tetravalent iron, aluminum and magnesium, and complex compounds and disalicyl ferrocene with silver and copper. The thermal stability of the complexes obtained was determined and it was shown that the greatest resistance to heat is possessed by complexes with beryllium, as well as with Mg and Al, which stand heating up to 200C without significant loss in weight. The least thermal stability was observed in the case of complexes with copper, which at 200C in the course of 5 minutes, lose 30% of their weight. It was established that the complexes of salicylates of ferrocene, in contrast to the corresponding monomer products, possess considerably higher magnetic susceptibility and higher electrical conductivity. (Author)

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