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Reactions of Chlorine Dioxide and Other Oxy-Chloro Compounds with Organic Compounds. Kinetics and Mechanisms of the Reaction Between Chlorite and Hypochlorous Acid in Aqueous Solution

机译：二氧化氯和其他氧氯化合物与有机化合物的反应。亚氯酸盐与次氯酸在水溶液中反应的动力学和机理

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The reaction of the formation of chlorine dioxide from hypochlorous acid and chlorite in aqueous solutions, which was studied in the present research is gHOCl + hClO2(-) yields pCl0w + qCl03(-) + rCl(-). Since chlorine dioxide, chlorite and hypochlorous acid have different absorption peaks in the ultra-violet range, the spectrophotometer was used as the method of analysis. Kinetic analysis of the concentration values of hypochlorous acid, chlorine dioxide and chlorite changing with time during the course of the reaction reveals that the rate of the overall reaction is first order with respect to the two reactants under the range of experimental conditions used. The yield of chlorine dioxide from chlorite varied from 35 to 65% within the experimental conditions described. It was observed that the majority of the chlorite comsumed was oxidized to chlorine dioxide or chlorate whereas the hypochlorous acid consumed was reduced to chloride. A mechanism is suggested in which Cl2O2 is the activated intermediate complex. This mechanism suggests that the formation of the intermediate is the slow rate determining step.

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Granstrom, M. L.; Israel, B. M.; Snow, W. B.; Lynch, M. E.;
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年度 1964
页码 p.1-2
总页数 2
原文格式 PDF
正文语种 eng
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关键词
WATER SUPPLIES ; OXIDIZERS ; CHLORINE COMPOUNDS ; CHLORITES ; PURIFICATION ; CHEMICAL PROPERTIES ; DIOXIDES ; CHEMICAL REACTIONS ; CHLORINE ; CHLORATES ; OXYCHLORIDES ; SODIUM COMPOUNDS ; ORGANIC COMPOUNDS ; REACTION KINETICS ; ULTRAVIOLET SPECTROSCOPY ; THERMODYNAMICS ; HEAT OF ACTIVATION ; BUFFERS (CHEMISTRY);

机译：供水;氧化剂;氯化合物;氯化物;纯化;化学性质;二氧化物;化学反应;氯;氯酸盐;氧氯化物;钠化合物;有机化合物;反应动力学;紫外光谱;热力学;活化热;缓冲剂（化学）;

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1. Mechanism Involving Hydrogen Sulfite Ions, Chlorite Ions, and Hypochlorous Acid as Key Intermediates of the Autocatalytic Chlorine Dioxide-Thiourea Dioxide Reaction [J] . Hu Ying, Horvath Attila K., Duan Sasa, European journal of inorganic chemistry . 2015,第30期

机译：亚硫酸氢根离子，亚氯酸根离子和次氯酸作为自催化二氧化氯-二氧化硫脲反应的关键中间体的机理
2. Kinetics and mechanisms of aqueous chlorine reactions with chlorite ion in the presence of chloride ion and acetic acid/acetate buffer [J] . Nicoson JS., Margerum DW. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2002,第2期

机译：氯离子和乙酸/乙酸缓冲液存在下氯水溶液与亚氯酸根离子反应的动力学和机理
3. Kinetics and mechanisms of the reactions of hypochlorous acid, chlorine, and chlorine monoxide with bromite ion [J] . Perrone TF., Hartz KEH., Wang L., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第19期

机译：次氯酸，氯和一氧化氯与溴酸根离子反应的动力学和机理
4. Comparative studies of chlorine dioxide reactions with muconic acid type structures, phenolic and non-phenolic lignin model compounds [C] . Y. HAMZEH, G. MORTHA, D. LACHENAL, Appita Annual Conference and Exhibition incorporating the ISWFPC(International Symposium on Wood, Fibre and Pulping Chemistry) vol.2: 13th ISWFPC Sessions - Oral Papers; 20050516-19; Auckland(NZ) . 2005

机译：具有粘康酸型结构，酚和非酚木质素模型化合物的二氧化氯反应的比较研究
5. The kinetics and mechanisms of some fundamental organic reactions of nitro compounds. [D] . Li, Zhao. 2012

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6. Reactions of aqueous chlorine and chlorine dioxide with model food compounds. [O] . M Y Fukayama, H Tan, W B Wheeler, 1986

机译：含水氯和二氧化氯与食品模型化合物的反应。
7. Reactions of aqueous chlorine and chlorine dioxide with model food compounds. [O] . Fukayama, M Y, Tan, H, Wheeler, W B, 1986

机译：含水氯和二氧化氯与食品模型化合物的反应。

Reactions of Chlorine Dioxide and Other Oxy-Chloro Compounds with Organic Compounds. Kinetics and Mechanisms of the Reaction Between Chlorite and Hypochlorous Acid in Aqueous Solution

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