首页> 美国政府科技报告 >Studies in Ivth Group Organometallic Chemistry. XVI. Synthesis of Organogermanium Compounds Containing the p-Phenylene Group. Some Infrared Characteristics of p-Phenylene Derivatives of Silicon, Germanium, Tin and Lead

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Studies in Ivth Group Organometallic Chemistry. XVI. Synthesis of Organogermanium Compounds Containing the p-Phenylene Group. Some Infrared Characteristics of p-Phenylene Derivatives of Silicon, Germanium, Tin and Lead

机译：第I组有机金属化学研究。十六。含有对亚苯基的有机锗化合物的合成。硅，锗，锡和铅的对苯撑衍生物的一些红外特征

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A few oligomeric and polymeric p-phenylenegermanes have been prepared by Wurtz-type condensation reactions from p-chlorophenyl and chloro-germanes. The oligomerio and polymeric products obtained have been characterized by infrared spectroscopy, elementary analysis and molecular weight determinations. Infrared spectra in the rocksalt region of phenyl and p-phenylene derivatives of silicon, germanium, tin and lead are discussed. The spectra of the p-phenylene compounds show some characteristic absorption bands shifting to lower frequencies as the weight of the metal atoms in the molecule increases. (Author)

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Leusink, A. J.; Noltes, J. G.; Budding, H. A.; Van Der Kerk, G. J. M.;
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年度 1964
页码 p.1-2
总页数 2
原文格式 PDF
正文语种 eng
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关键词
Metalorganic compounds ; Polymers ; Germanium compounds ; Polymerization ; Aromatic compounds ; Condensation reactions ; Chlorine compounds ; Spectra(Infrared) ; Chemical analysis ; Molecular weight ; Silanes ; Tin compounds ; Lead compounds ; Band spectrum ; Netherlands;

机译：金属有机化合物;聚合物;锗化合物;聚合;芳香族化合物;缩合反应;氯化合物;光谱（红外线）;化学分析;分子量;硅烷;锡化合物;铅化合物;谱带;荷兰;

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1. Synthesis of π -conjugated polymers via regioregular organometallic polymers 2. Transformation of titanacyclopentadiene-containing polymer into poly(p-phenylene) derivative [J] . Tomoko Kino, Hiroki Nishiyama, Ikuyoshi Tomita Applied Organometallic Chemistry . 2010,第8期

机译：通过区域规则的有机金属聚合物合成π共轭聚合物2.含钛环戊二烯的聚合物转变为聚对苯撑衍生物
2. Synthesis of π-conjugated polymers via regioregular organometallic polymers 2. Transformation of titanacyclopentadiene- containing polymer into poly(p-phenylene) derivative [J] . Tomoko Kino Hiroki Nishiyama Ikuyoshi Tomita Applied Organometallic Chemistry . 2010,第8期

机译：通过区域规则的有机金属聚合物合成π共轭聚合物2.含钛环戊二烯的聚合物转变为聚对苯撑衍生物
3. Electron impact and chemical ionisation mass spectrometry in the characterisation of organometallic silicon, germanium, tin and lead compounds [J] . Constantine SP., Bollen BG., Cardin DJ. Rapid Communications in Mass Spectrometry: RCM . 2000,第5期

机译：电子冲击和化学电离质谱用于有机金属硅，锗，锡和铅化合物的表征
4. Synthesis and Characterization of Large Single Crystals of Silicon and Germanium Clathrate-II Compounds and a New Tin Compound with Clathrate Layers [C] . Svilen Bobev, Slavi C. Sevov MRS Meeting . 2001

机译：硅和锗克拉酸酯-II型化合物的大单晶的合成与表征及具有克拉碱层的新型锡化合物
5. Computational studies on group 14 elements (carbon, silicon and germanium) in organometallic and biological compounds. [D] . Yu, Liwen. 2007

机译：对有机金属和生物化合物中第14组元素（碳，硅和锗）的计算研究。
6. The microsomal metabolism of the organometallic derivatives of the group-IV elements germanium tin and lead. [O] . R A Prough, M A Stalmach, P Wiebkin, 1981

机译：IV族元素的有机金属衍生物锗锡和铅的微粒体代谢。
7. Chemistry of Germanium-Characteristics and Similarity as a Group 14 Element. Character of Organogermanium Compounds in Organo Group 14 Element Compounds and Their Application to Organic Synthesis. [O] . Yoshiro SATO, Sumie ANDO 1994

机译：锗的化学特征和相似性作为14个元素。有机基金14元化合物中有机合金化合物的特征及其在有机合成中的应用。
8. Studies in Ivth Group Organmetallic Chemistry. IX. Synthesis of Organosilicon Compounds and Polymers Containing the p-Phenylene Group [R] . Noltes, H. G., Van Der Kerk, G. J. M. 1962

机译：Ivth Group Organmetallic Chemistry的研究。 IX。含有对亚苯基的有机硅化合物和聚合物的合成

Studies in Ivth Group Organometallic Chemistry. XVI. Synthesis of Organogermanium Compounds Containing the p-Phenylene Group. Some Infrared Characteristics of p-Phenylene Derivatives of Silicon, Germanium, Tin and Lead

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