Correlation of Limiting Currents under Free Convection Conditions.

机译：自由对流条件下极限电流的相关性。

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This paper is concerned with limiting rates of deposition of copper ions at a vertical cathode in an unstirred solution. In such a system, natural convection, or spontaneous stirring, results from density changes which accompany concentration changes in the region of the electrode. The limiting process is controlled by the maximum rate of mass transfer of copper between bulk solution and the electrode surface. A more detailed discussion of mass transfer phenomena in electrochemical problems has been presented in an earlier paper. Natural convection usually involves laminar motion of the fluid so that the over-all process requires consideration of the simultaneous action of molecular diffusion and convective flow. In steady-state free convection, the main resistance to mass transfer is associated with a relatively small region of fluid in the vicinity of the electrode, and the concentration of the bulk-solution remains constant. (KAR) P. 2.

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Wilke, C. R.; Eisenberg, M.; Tobias, C. W.;
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年度 1953
页码 1-12
总页数 12
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Ions; Convection; Electrochemistry; Current density; Copper; Mass transfer; Steady state; Resistance; Rates; Deposition; Cathodes; Correlation; Limitations; Electrodes; Fluids; Flow; Synchronism; Currents; Ionic current; Reprints; Copper deposition;

机译：离子;对流;电化学;电流密度;铜;传质;稳态;电阻;速率;沉积;阴极;相关性;限制;电极;流体;流动;同步;电流;离子电流;重印;铜沉积;

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Correlation of Limiting Currents under Free Convection Conditions.

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