首页> 美国政府科技报告 >Preparation of Composite Fluoropolymers with Enhanced Dewetting Using Fluorinated Silsesquioxanes as Drop-In Modifiers (Preprint)
【24h】

Preparation of Composite Fluoropolymers with Enhanced Dewetting Using Fluorinated Silsesquioxanes as Drop-In Modifiers (Preprint)

机译:使用氟化倍半硅氧烷作为嵌入式改性剂制备具有增强脱湿性的复合含氟聚合物(预印本)

获取原文

摘要

Composite fluoropolymers were prepared by solvent blending fluorinated POSS (F-POSS) with perfluorocyclobutyl (PFCB) aryl ether polymers. The semifluorinated PFCB aryl ether polymers were shown to be hydrophobic, but demonstrated complete wetting by hydrocarbon-based liquids. Upon the incorporation of F-POSS as a drop-in modifier at low weight percent loadings, the composite fluoropolymer spin cast films exhibited increased water in addition to hydrocarbon repellency as determined by contact angle analysis. Composite film surface characterization included SEM and AFM analysis which showed excellent F-POSS dispersion and increased surface roughness. Thermal properties of the blended films were performed using DSC and demonstrated the incorporation of F-POSS did not affect the bulk matrix properties inherent of PFCB aryl ether polymers. This work demonstred that optimized F-POSS PFCB aryl ether polymer blend formulations have potential use as hydro- and oleophobic materials for seals, fibers, and coatings.

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号