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Time-Resolved Studies of Photoinduced Birefringence in Azobenzene Dye- Doped Polymer Films.

机译:偶氮苯染料掺杂聚合物薄膜中光诱导双折射的时间分辨研究。

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We measured transient photoinduced birefringence (delta n) in various azobenzene dye films by pumping with a nanosecond pulse at 532nm and probing at 633 nm. The switch-on times for the photoinduced birefringence range from nanoseconds to milliseconds and are systematically related with the lowest optical transition energies for those films. Moreover, our results suggest that the transient photoinduced birefringence measurement is a convenient way to determine the relative energies of pi-pi* and n-pi* states in azo-based materials.

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