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Probing Metal Cluster and Metal Oxide Cluster Interactions with Organo- Sulfur and Organo-Phosphorous Molecules using Mass Spectrometry and Anion PES

机译：利用质谱和阴离子pEs探测金属团簇和金属氧化物团簇与有机硫和有机磷分子的相互作用

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Mass spectrometry anion photoelectron spectroscopy and density functional theory calculations have been applied to several aluminum oxide cluster complexes. The reactivity of several 'magic' clusters (i.e. those species that dominate the mass spectrum) toward water and methanol has been explored and for one system A1303- + 1 and 2 H20 the reaction products have been determined by comparing experimental and computational results. The Density functional theory calculations have been successfully applied to a number of transition metal complexes with the intent that they will be applied in the future to transition metal disulfide cluster systems. Preliminary results on the spectra of larger hypermetallic aluminum oxide clusters are presented.

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Jarrold, C. C.;
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年度 2002
页码 1-6
总页数 6
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Clustering; Metal complexes; Interactions; Reactivities; Aluminum oxides; Reactants(Chemistry); Organophosphates; Mass spectrometry; Organic sulfur compounds; Density functional theory;

机译：聚类;金属配合物;相互作用;反应活性;氧化铝;反应物（化学）;有机磷酸盐;质谱;有机硫化合物;密度泛函理论;

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专利

1. Cationization of simple organic molecules by singly-charged Ag-3(+) cluster ions in matrix-assisted laser desorption/ionization mass spectrometry: Metal cluster-molecule interactions [J] . Keki S, Nagy L, Deak G, Journal of the American Society for Mass Spectrometry . 2004,第6期

机译：基质辅助激光解吸/电离质谱法中单电荷Ag-3（+）簇离子对简单有机分子的阳离子化：金属簇-分子相互作用
2. Structure and dissociation characteristics of metal chloride anion clusters containing redox-active metal ions studied by laser desorption and electrospray ionization mass spectrometry and ab initio calculations [J] . Ruttink P.J.A., Terlouw J.K., Luider T.M., Journal of mass spectrometry: JMS . 2011,第2期

机译：通过激光解吸，电喷雾电离质谱和从头算计算研究了含有氧化还原活性金属离子的金属氯化物阴离子簇的结构和解离特性
3. Interactions of a Nucleoside Cytidine with Metal Ions in Water Observed through Mass Spectrometry: Clustering Controlled by Electrostatic Interaction and Coordinating Interaction [J] . Shunsuke Mochizuki, Akihiro Wakisaka The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2003,第23期

机译：质谱观察到的核苷胞苷与水中金属离子的相互作用：由静电相互作用和配位相互作用控制的聚类
4. Electrospray Ionization Mass Spectrometry of the Interaction of Oligonucleotides with Metals, Small Molecules and Drugs [C] . Janna Anichina, Diethard K. Bohme ASMS Conference on Mass Spectrometry and Allied Topics . 2007

机译：电喷雾电离质谱与金属，小分子和药物的寡核苷酸相互作用
5. Spectroscopic and Computational Study of Metal Oxide Cluster Anions and Their Reactivities with Small Molecules. [D] . Ray, Manisha. 2017

机译：金属氧化物簇阴离子及其与小分子的反应性的光谱和计算研究。
6. Metallocages for Metal Anions: Highly Charged Co@Ge95− and Ru@Sn96− Clusters Featuring Spherically Encapsulated Co1− and Ru2− Anions [O] . M. Sc. Benedikt J. L. Witzel, Dr. Wilhelm Klein, M. Sc. Jasmin V. Dums, -1

机译：金属阴离子的金属位置：具有球形封装的Co1-和Ru2-阴离子的高电荷Co @ Ge9 5−和Ru @ Sn9 6−团簇
7. Cationization of simple organic molecules by singly-charged Ag3+ cluster ions in matrix-assisted laser desorption/ionization mass spectrometry: metal cluster-molecule interactions**Dedicated to Professor Sándor Antus on the occasion of his 60th birthday. [O] . Kéki Sándor, Nagy Lajos, Deák György, 2004

机译：在基质辅助激光解吸/电离质谱中通过单电荷的Ag3 +簇离子对简单有机分子的阳离子化：金属簇-分子相互作用**献给SándorAntus教授60岁生日。

Probing Metal Cluster and Metal Oxide Cluster Interactions with Organo- Sulfur and Organo-Phosphorous Molecules using Mass Spectrometry and Anion PES

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