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Electroactive and Photoactive Nanostructured Materials from Self-Organized Rod-Coil Copolymers: Synthesis and Electroluminescent Devices

机译：自组织棒 - 线圈共聚物的电活性和光活性纳米结构材料：合成和电致发光器件

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Electroluminescent ternary and binary rod-coil copolymer systems have been synthesized, characterized, and used to explore the effects of solid state supramolecular structure and morphology on the mechanism and quantum efficiency of electroluminescence. Enhanced electroluminescence due to efficient electronic energy transfer was observed in ternary rod-coil-rod copolymer systems containing two rodlike segments with different excitation energies, compared to the corresponding binary copolymers. Binary rod-coil copolymers which incorporate, into the rodlike segments, moieties that exhibit excited state intramolecular proton transfer were found to be electroluminescent via a novel mechanism, electrically generated intramolecular proton transfer (EGIPT). The inherent population inversion in the EGIPT process together with the observed stimulated emission imply the feasibility of electrically induced lasing in this class of materials. EGIPT was found to occur in only rod-coil copolymers with low rod-to-coil molar ratios, suggesting the profound effect of supramolecular structure.

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Tarkka, R. M. ; Chen, X. L. ; Jenekhe, S. A.;
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年度 1998
页码 1-28
总页数 28
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Composite materials; Copolymers; Molecular structure; Molecule molecule interactions; Synthesis; Polymers; Excitation; Morphology; Energy transfer; Electron energy; Naval research; Quantum efficiency; Inversion; Solid state chemistry; Proton reactions;

机译：复合材料;共聚物;分子结构;分子分子相互作用;合成;聚合物;激发;形态学;能量转移;电子能;海军研究;量子效率;反转;固态化学;质子反应;

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专利

1. ELECTROACTIVE AND PHOTOACTIVE ROD-COIL COPOLYMERS - DESIGN, SYNTHESIS, AND SUPRAMOLECULAR REGULATION OF PHOTOPHYSICAL PROPERTIES [J] . Osaheni JA., Jenekhe SA. Journal of the American Chemical Society . 1995,第28期

机译：电和光敏杆状线圈共聚物-光物理性质的设计，合成和超分子调控
2. Block Copolymers Containing Conjugated Polymer and Polypeptide Sequences:Synthesis and Self-Assembly of Electroactive and Photoactive Nanostructures [J] . Xiangxing Kong, samson A.Jenekhe Macromolecules . 2004,第22期

机译：包含共轭聚合物和多肽序列的嵌段共聚物：电活性和光活性纳米结构的合成和自组装
3. Synthesis of Poly(paraphenylene vinylene)-Polystyrene-Based Rod-Coil Block Copolymer by Atom Transfer Radical Polymerization: Toward a Self-Organized Lamellar Semiconducting Material [J] . Brochon C, Sary N, Mezzenga R, Journal of Applied Polymer Science . 2008,第6期

机译：原子转移自由基聚合合成聚对苯乙炔-聚苯乙烯基棒状嵌段共聚物：一种自组织的层状半导体材料
4. Electroactiv eand photoactive nanostructuted mateirals form self-organizing rod-coil coplymers: synthesis and electroluminescent devices [C] . Richard M.Tarkka, X.Linda Chen, Samson A.Jenekhe Photonic and optoelectronic polymers . 1995

机译：电活化和光活化纳米结构材料形成自组织棒状线圈聚合物：合成和电致发光器件
5. Functional block copolymers containing photoactive and electroactive segments: Synthesis, characterization and self -assembly study [D] . Li, Kun 2007

机译：含有光活性和电活性链段的功能性嵌段共聚物：合成，表征和自组装研究
6. PANI Branches onto Donor-Acceptor Copolymers: Synthesis Characterization and Electroluminescent Properties of New 2D-Materials [O] . Ignacio A. Jessop, Fernando R. Díaz, Claudio A. Terraza, 2018

机译：PANI分支到给体-受体共聚物上：新型2D材料的合成表征和电致发光性能
7. Block Copolymers Containing Conjugated Polymer and Polypeptide Sequences: Synthesis and Self-Assembly of Electroactive and Photoactive Nanostructures [O] . -1

机译：含有缀合聚合物和多肽序列的嵌段共聚物：电活性和光活性纳米结构的合成和自组装

Electroactive and Photoactive Nanostructured Materials from Self-Organized Rod-Coil Copolymers: Synthesis and Electroluminescent Devices

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